#------------------------------------------------------------------------------ #$Date: 2019-03-21 05:50:50 +0200 (Thu, 21 Mar 2019) $ #$Revision: 214251 $ #$URL: file:///home/coder/svn-repositories/cod/cif/1/55/07/1550772.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_1550772 loop_ _publ_author_name 'El-Hiti, Gamal A.' 'Abdel-Wahab, Bakr F.' 'Alqahtani, Alaa' 'Hegazy, Amany S.' 'Kariuki, Benson M.' _publ_section_title ; 4-(Benzofuran-2-yl)-2-[3-(4-chlorophenyl)-5-(4-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl]thiazole ; _journal_coeditor_code HB4289 _journal_issue 3 _journal_name_full IUCrData _journal_page_first x190359 _journal_paper_doi 10.1107/S2414314619003596 _journal_volume 4 _journal_year 2019 _chemical_formula_iupac 'C26 H17 Cl F N3 O S' _chemical_formula_moiety 'C26 H17 Cl F N3 O S' _chemical_formula_sum 'C26 H17 Cl F N3 O S' _chemical_formula_weight 473.93 _chemical_name_systematic 4-(Benzofuran-2-yl)-2-[3-(4-chlorophenyl)-5-(4-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl]thiazole _space_group_crystal_system monoclinic _space_group_IT_number 14 _space_group_name_Hall '-P 2ybc' _space_group_name_H-M_alt 'P 1 21/c 1' _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary direct _audit_creation_method SHELXL-2018/1 _cell_angle_alpha 90 _cell_angle_beta 96.390(9) _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 6.6631(6) _cell_length_b 15.2297(17) _cell_length_c 22.431(3) _cell_measurement_reflns_used 1999 _cell_measurement_temperature 296(2) _cell_measurement_theta_max 23.2950 _cell_measurement_theta_min 3.7320 _cell_volume 2262.1(4) _computing_cell_refinement ; CrysAlis PRO (Rigaku OD, 2015) ; _computing_data_collection ; CrysAlis PRO (Rigaku OD, 2015) ; _computing_data_reduction ; CrysAlis PRO (Rigaku OD, 2015) ; _computing_molecular_graphics ; ORTEP-3 for Windows and WinGX (Farrugia, 2012) ; _computing_publication_material ; ORTEP-3 for Windows and WinGX (Farrugia, 2012), and CHEMDRAW Ultra (Cambridge Soft, 2001) ; _computing_structure_refinement ; SHELXL2018 (Sheldrick, 2015) ; _computing_structure_solution ; SHELXS (Sheldrick, 2008) ; _diffrn_ambient_temperature 296(2) _diffrn_measured_fraction_theta_full 0.998 _diffrn_measured_fraction_theta_max 0.998 _diffrn_measurement_device_type 'Rigaku OD SuperNova Dual source diffractometer with an Atlas detector' _diffrn_measurement_method '\w scans' _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0418 _diffrn_reflns_av_unetI/netI 0.0588 _diffrn_reflns_limit_h_max 8 _diffrn_reflns_limit_h_min -6 _diffrn_reflns_limit_k_max 17 _diffrn_reflns_limit_k_min -19 _diffrn_reflns_limit_l_max 22 _diffrn_reflns_limit_l_min -28 _diffrn_reflns_number 10799 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 26.372 _diffrn_reflns_theta_min 3.355 _diffrn_standards_decay_% 0 _diffrn_standards_interval_count 0 _diffrn_standards_interval_time 0 _diffrn_standards_number 0 _exptl_absorpt_coefficient_mu 0.294 _exptl_absorpt_correction_T_max 0.997 _exptl_absorpt_correction_T_min 0.990 _exptl_absorpt_correction_type gaussian _exptl_absorpt_process_details ; (CrysAlis PRO; Rigaku OD, 2015) ; _exptl_crystal_colour colourless _exptl_crystal_density_diffrn 1.392 _exptl_crystal_description needle _exptl_crystal_F_000 976 _exptl_crystal_size_max 0.460 _exptl_crystal_size_mid 0.189 _exptl_crystal_size_min 0.113 _refine_diff_density_max 0.169 _refine_diff_density_min -0.209 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.030 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 298 _refine_ls_number_reflns 4617 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 1.030 _refine_ls_R_factor_all 0.1247 _refine_ls_R_factor_gt 0.0603 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0542P)^2^+0.6825P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1345 _refine_ls_wR_factor_ref 0.1708 _reflns_number_gt 2323 _reflns_number_total 4617 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file hb4289sup1.cif _cod_data_source_block I _cod_database_code 1550772 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_estimated_absorpt_t_min 0.877 _shelx_estimated_absorpt_t_max 0.968 _shelx_hkl_file ; 0 0 4 53118.7 498.651 3 0 0 5 85.3798 36.7087 3 0 0 6 20170.9 416.175 2 0 0 6 20838.3 385.214 3 0 0 7 125.756 39.8027 2 0 0 7 116.790 39.5992 3 0 0 8 2265.88 146.911 3 0 0 8 2291.37 166.263 2 0 0 9 62.7393 37.3313 2 0 0 9 38.4053 23.6816 3 0 0 10 39830.0 695.058 3 0 0 10 39744.0 785.509 2 0 0 -11 1672.04 156.697 3 0 0 11 753.081 122.884 2 0 0 12 8270.17 397.035 2 0 0 13 1119.09 160.189 2 0 0 14 1618.26 191.804 2 0 0 -14 1915.20 178.748 3 0 0 -15 1011.96 138.540 3 0 0 15 650.435 132.968 2 0 0 -16 581.613 108.773 3 0 0 16 418.238 105.555 2 0 0 -17 513.792 116.061 3 0 0 -18 345.697 92.7029 3 0 0 -19 316.330 90.0384 3 0 0 -20 528.334 118.143 3 0 0 -21 129.842 63.8343 3 0 0 -22 572.212 129.625 3 0 0 -23 134.691 62.1498 3 0 0 -24 115.061 56.9172 3 0 0 -25 174.299 80.8262 3 0 0 -26 32.5667 47.0180 3 0 0 -27 92.0343 46.9656 3 0 0 -28 96.1345 57.9071 3 0 0 -29 226.969 105.705 3 0 1 4 2105.07 113.672 2 0 1 4 2187.28 97.9225 3 0 1 5 7417.93 235.713 2 0 1 5 7536.39 204.923 3 0 1 6 447.534 63.9210 2 0 1 6 457.156 56.9926 3 0 1 7 19054.2 447.946 2 0 1 7 19082.7 391.130 3 0 1 8 768.134 98.0003 2 0 1 8 763.080 85.9528 3 0 1 9 1.67514 13.9967 3 0 -1 -9 24.1734 21.1655 3 0 1 9 12.2808 20.1876 2 0 -1 -10 708.923 94.0625 3 0 1 10 766.284 98.8256 3 0 1 10 776.791 112.393 2 0 1 11 2376.80 198.013 2 0 1 11 2304.95 174.759 3 0 -1 -11 2345.84 166.154 3 0 -1 12 1564.28 175.151 2 0 1 12 1712.87 179.858 2 0 1 12 1574.15 153.274 3 0 -1 13 5275.03 333.512 2 0 1 13 4989.41 282.612 3 0 1 13 4859.14 309.858 2 0 1 -14 523.441 94.5821 3 0 -1 14 401.697 101.575 2 0 1 14 460.777 92.2691 3 0 1 14 439.716 101.192 2 0 -1 15 1512.81 194.455 2 0 -1 -15 1421.53 155.746 3 0 1 15 1210.10 172.985 2 0 1 -15 1323.10 152.895 3 0 1 16 537.253 118.082 2 0 -1 -16 539.366 97.4157 3 0 1 -16 515.661 100.634 3 0 -1 16 536.933 121.934 2 0 1 -17 1600.31 187.995 3 0 -1 -17 1590.45 176.424 3 0 -1 -18 2808.09 243.264 3 0 1 -18 2642.78 243.265 3 0 1 -19 287.109 94.0250 3 0 -1 -19 301.144 91.6216 3 0 -1 -20 879.758 146.185 3 0 1 -20 796.365 142.422 3 0 -1 -21 111.539 50.2155 3 0 1 -21 59.6257 19.9966 3 0 -1 -22 9.90547 27.2034 3 0 1 -22 7.22077 24.9261 3 0 1 -23 133.854 65.5293 3 0 -1 -23 244.428 87.4903 3 0 1 -24 234.572 86.5654 3 0 -1 -24 268.390 93.7015 3 0 -1 -25 217.613 84.6989 3 0 1 -25 282.704 103.882 3 0 1 -26-50.5055 47.1847 3 0 -1 -26 31.4880 33.0601 3 0 -1 -27 42.9471 45.7444 3 0 1 -27-58.3363 65.7584 3 0 1 -28 1.56550 37.5045 3 0 -1 -28-27.6619 28.6018 3 0 1 -29 154.296 92.4274 3 0 -1 -29 135.255 92.7496 3 0 2 3 5148.14 162.967 2 0 2 3 5445.23 132.769 3 0 2 4 1331.72 91.2955 2 0 2 4 1368.11 76.4155 3 0 2 5 766.393 76.6713 2 0 2 5 808.581 66.8783 3 0 2 6 6860.25 250.841 2 0 -2 -6 6959.93 206.544 3 0 2 6 6994.75 215.414 3 0 2 7 47.5883 25.8518 2 0 -2 -7 21.5218 8.89367 3 0 2 7 58.1620 23.3862 3 0 -2 -8 13629.9 332.049 3 0 2 8 13504.8 402.622 2 0 2 8 13620.2 352.700 3 0 2 9 2.66661 11.3441 3 0 -2 -9 46.2787 40.9012 3 0 2 9 46.3641 33.2258 2 0 -2 -10 4614.27 220.027 3 0 2 10 4745.42 234.048 3 0 2 10 4634.84 262.680 2 0 2 11 2651.32 210.780 2 0 2 11 2755.32 188.954 3 0 -2 -11 2610.02 175.403 3 0 2 12 35.5449 31.5494 2 0 2 12 10.7635 16.0957 3 0 2 13 3514.55 234.447 3 0 2 13 3659.87 268.055 2 0 2 -14 2764.91 220.578 3 0 2 14 2772.22 245.385 2 0 2 14 2831.87 218.934 3 0 2 -15 1484.58 171.860 3 0 2 15 1405.05 186.316 2 0 -2 -15 1555.00 158.642 3 0 -2 15 1710.18 214.527 2 0 2 15 1386.41 163.134 3 0 -2 16 164.214 75.4557 2 0 2 16 78.3107 51.7323 3 0 2 -16 178.080 59.1013 3 0 -2 -16 112.418 61.8804 3 0 2 16 130.789 65.3491 2 0 2 -17 5794.82 356.110 3 0 2 17 6278.98 363.143 3 0 -2 -17 6202.23 337.301 3 0 2 -18 2552.28 251.371 3 0 -2 -18 2721.92 241.459 3 0 2 -19 2971.79 272.950 3 0 -2 -19 3297.01 266.425 3 0 -2 -20 62.5236 38.0535 3 0 2 -20 200.688 80.1321 3 0 -2 -21-35.0940 63.9549 3 0 2 -21 28.5939 24.7114 3 0 -2 -22-44.6505 53.0300 3 0 2 -22 58.0050 52.2646 3 0 -2 -23-23.6367 45.7020 3 0 2 -23 147.291 67.9837 3 0 -2 -24-11.8771 23.8941 3 0 2 -24 21.7230 36.9437 3 0 -2 -25-27.2732 36.8377 3 0 2 -25 90.2462 59.6195 3 0 -2 -26 94.9119 57.2574 3 0 2 -26 152.953 80.2314 3 0 2 -27 15.5679 24.5072 3 0 -2 -27 39.0540 39.7142 3 0 -2 -28 37.6475 50.7979 3 0 2 -28-26.0157 51.4253 3 0 -2 -29 1.38550 25.0607 3 0 -2 -30 0.12118 34.7452 3 0 3 0 23.6107 17.0443 2 0 3 -1 2980.48 136.710 2 0 3 1 2748.53 109.906 2 0 3 2 17909.0 290.790 2 0 3 3 2688.48 123.678 2 0 3 4 59715.0 644.252 2 0 3 4 60764.9 527.779 3 0 3 5 14090.1 337.186 2 0 3 5 13686.2 274.067 3 0 -3 -5 14083.1 273.893 3 0 -3 -6 23832.1 384.870 3 0 3 6 23788.7 394.415 3 0 3 6 23055.0 470.037 2 0 -3 -7 19094.5 368.762 3 0 3 7 19689.5 466.809 2 0 3 7 19623.2 389.506 3 0 -3 -8 15076.8 347.644 3 0 3 8 14959.7 434.324 2 0 3 8 14712.5 361.945 3 0 3 -8 14362.9 249.837 1 0 3 9 21367.6 547.311 2 0 -3 -9 21366.3 441.055 3 0 3 9 21178.0 459.923 3 0 3 10 21625.1 578.686 2 0 -3 -10 22372.9 476.423 3 0 3 10 22182.9 504.819 3 0 -3 -11 351.442 73.6693 3 0 3 11 366.572 80.7157 2 0 3 11 319.922 64.1491 3 0 -3 -12 847.818 102.276 3 0 3 12 909.450 114.366 3 0 3 12 859.150 124.872 2 0 3 13 1277.79 139.598 3 0 3 13 1381.43 168.437 2 0 3 14 22.8625 34.0134 2 0 3 14 42.2901 36.8688 3 0 3 15 295.289 74.6487 3 0 -3 -15 405.749 80.1158 3 0 3 -15 425.006 93.4352 3 0 3 15 308.826 85.8429 2 0 3 -16 1368.46 181.011 3 0 3 16 1411.15 166.559 3 0 -3 -16 1466.88 158.485 3 0 3 16 1335.38 185.973 2 0 -3 -17 4387.69 283.157 3 0 3 17 4225.13 301.466 3 0 3 -17 3966.63 301.370 3 0 3 18 149.733 77.2296 3 0 -3 -18 149.395 76.6375 3 0 3 -18 149.800 83.6739 3 0 -3 -19 1069.34 148.062 3 0 3 -19 1141.99 172.123 3 0 3 -20 882.315 156.395 3 0 -3 -20 759.851 131.486 3 0 3 -21 193.254 74.5890 3 0 -3 -21 125.416 58.9412 3 0 -3 -22 225.177 77.6501 3 0 3 -22 300.175 101.040 3 0 3 -23 68.5120 77.1878 3 0 -3 -23 19.1327 22.0266 3 0 -3 -24 4.92106 23.9457 3 0 3 -24 41.8479 54.4708 3 0 -3 -25-52.1942 56.1630 3 0 3 -25 87.2717 54.7449 3 0 3 -26 18.9083 74.3306 3 0 -3 -26-5.93693 29.1667 3 0 3 -27 25.1033 28.0425 3 0 -3 -27-31.2353 37.7684 3 0 3 -28-56.0138 55.9079 3 0 -3 -28-10.4214 30.8757 3 0 -3 -29 18.4156 40.2534 3 0 -3 -30 132.373 85.1944 3 0 4 0 208888. 1147.86 2 0 4 1 256282. 1247.11 2 0 4 -1 266170. 1439.70 2 0 4 2 1804.12 107.675 2 0 4 3 1592.98 102.157 2 0 4 4 868.307 79.6373 2 0 4 5 2844.60 154.274 2 0 4 5 2775.35 127.432 3 0 4 6 1440.64 118.475 2 0 4 6 1394.46 96.6765 3 0 4 7 38.6397 18.8069 3 0 4 7 58.9147 25.1263 2 0 4 8 119.262 39.0701 2 0 4 8 137.171 31.1629 3 0 -4 -8 88.6948 20.5744 3 0 -4 -9 7992.30 273.178 3 0 4 9 8000.81 284.377 3 0 4 9 7913.40 337.004 2 0 4 -10 2514.04 116.382 1 0 4 10 2715.61 209.211 2 0 4 10 2648.33 171.051 3 0 -4 -10 2653.20 164.804 3 0 4 11 118.911 37.4557 3 0 4 -11 112.120 18.4125 1 0 4 11 108.971 39.3297 2 0 -4 -11 140.223 35.3556 3 0 4 12 431.024 77.2823 3 0 4 12 417.842 90.7623 2 0 -4 -12 451.313 76.7577 3 0 4 13 6612.36 371.289 2 0 4 13 6348.39 313.152 3 0 4 14 391.399 83.6687 3 0 4 14 343.223 93.5471 2 0 4 -14 452.784 101.786 3 0 -4 -15 1280.93 138.683 3 0 4 -15 1272.98 162.822 3 0 4 15 1309.06 153.588 3 0 4 15 1179.23 172.822 2 0 4 16 364.275 110.307 2 0 -4 -16 465.190 87.9655 3 0 4 16 360.570 92.2514 3 0 4 -16 436.145 124.342 3 0 -4 -17 516.102 97.0021 3 0 4 17 556.123 115.029 3 0 4 -17 638.897 124.711 3 0 4 18 96.3377 52.5710 3 0 -4 -18 173.696 60.8743 3 0 4 -18 213.561 74.5444 3 0 4 -19 0.57989 31.5912 3 0 -4 -19 65.8202 39.5026 3 0 -4 -20-35.3745 37.9708 3 0 4 -20-52.0163 52.2239 3 0 4 -21-30.2008 56.4446 3 0 -4 -21 30.9256 36.2376 3 0 -4 -22 91.1617 50.7171 3 0 4 -22 49.3732 33.6132 3 0 -4 -23 173.226 69.0820 3 0 4 -23 101.139 50.2483 3 0 -4 -24 11.1379 25.1093 3 0 4 -24 2.57218 26.2859 3 0 4 -25 171.168 85.1727 3 0 -4 -25 136.131 79.5463 3 0 4 -26 134.050 96.0517 3 0 -4 -26 67.7365 51.6820 3 0 4 -27 14.9992 49.0655 3 0 -4 -27 47.9148 47.1077 3 0 -4 -28 58.2154 53.9198 3 0 -4 -29 126.706 94.0111 3 0 -4 -30 49.3637 70.5154 3 0 5 0-8.14669 23.8937 2 0 -5 0 125.027 37.8399 2 0 -5 -1 52601.6 626.277 2 0 -5 1 53310.0 626.045 2 0 5 -1 54568.4 711.819 2 0 5 1 54944.0 652.934 2 0 -5 2 6086.41 221.352 2 0 5 2 6246.38 218.567 2 0 -5 -2 5923.71 224.673 2 0 5 3 6.57558 9.28352 2 0 -5 3 41.4573 18.7892 2 0 -5 -3 0.59978 11.4262 2 0 -5 -4 13232.1 353.709 2 0 5 4 13171.6 329.222 2 0 -5 -5 1811.52 140.110 2 0 5 5 1790.90 128.035 2 0 5 5 1796.63 110.097 3 0 -5 -6 6885.88 293.506 2 0 5 6 7091.69 225.864 3 0 5 6 7238.18 270.893 2 0 5 7 2098.72 155.984 2 0 -5 -7 1904.83 159.467 2 0 5 7 1945.21 126.668 3 0 5 8 4172.76 233.819 2 0 5 8 4450.86 201.911 3 0 -5 -8 4226.11 245.645 2 0 5 9 2778.64 169.225 3 0 5 9 2878.85 202.781 2 0 5 10 4.55466 20.1335 2 0 5 10 35.7779 21.3887 3 0 5 11 422.298 83.3429 2 0 -5 -11 435.816 69.6165 3 0 5 11 427.266 73.8402 3 0 5 -12 31.6424 13.2433 1 0 5 12 25.9675 16.0135 3 0 5 12 47.5102 28.7406 2 0 -5 -12 16.7502 14.7459 2 0 -5 -13 233.796 83.0942 2 0 5 13 135.086 54.4293 2 0 5 13 213.385 59.9107 3 0 5 14 2854.14 252.739 2 0 5 14 3196.02 231.938 3 0 -5 -14 2974.71 261.764 2 0 5 -14 3267.88 264.271 3 0 -5 -15 196.750 53.1033 3 0 5 15 163.052 55.0931 3 0 5 -15 257.965 94.1932 3 0 5 15 235.456 80.3303 2 0 5 16 3658.62 267.441 3 0 5 -16 4137.05 309.087 3 0 -5 -16 3658.73 239.905 3 0 5 17 28.1222 41.9399 3 0 -5 -17 55.9002 46.3096 3 0 5 -17 94.9766 53.7958 3 0 5 -18-7.05838 29.4661 3 0 -5 -18 18.8005 34.1466 3 0 5 18-12.0669 15.8561 3 0 5 -19 227.084 82.7735 3 0 5 19 353.519 93.8685 3 0 -5 -19 405.653 92.8141 3 0 5 -20-55.0564 49.2742 3 0 -5 -20-10.6246 14.8270 3 0 -5 -21 34.8673 27.3330 3 0 5 -21-70.7087 56.4295 3 0 5 -22 376.255 109.063 3 0 -5 -22 356.599 88.5357 3 0 5 -23 54.5913 46.9143 3 0 -5 -23-7.74081 22.3722 3 0 5 -24 28.3829 53.5502 3 0 -5 -24 8.83467 16.7076 3 0 -5 -25-20.3701 44.5163 3 0 5 -25 4.29349 29.4329 3 0 5 -26 61.1682 55.3321 3 0 -5 -26 87.1513 50.6912 3 0 -5 -27-67.0867 49.1575 3 0 5 -27 27.5612 44.0611 3 0 -5 -28 120.442 74.6534 3 0 -5 -29 100.442 73.6292 3 0 -5 -30 100.225 81.7471 3 0 -6 0 7197.01 242.145 2 0 6 0 7410.98 268.220 2 0 6 1 2778.47 162.768 2 0 -6 1 2955.21 161.002 2 0 6 -1 2996.90 182.261 2 0 -6 -1 2989.45 158.909 2 0 -6 2 3124.21 168.511 2 0 6 2 3307.27 176.550 2 0 -6 -2 3316.06 172.377 2 0 -6 3 5195.09 232.714 2 0 -6 -3 5582.64 232.812 2 0 6 3 5638.64 225.111 2 0 -6 4 10872.0 370.197 2 0 -6 -4 11680.3 348.964 2 0 6 4 11298.5 328.815 2 0 -6 -5 1448.87 130.049 2 0 6 5 1335.78 117.494 2 0 6 6 5.29659 11.1255 3 0 6 6-13.7621 34.9057 2 0 -6 -6 40.8458 24.0118 2 0 6 7 2995.69 190.092 2 0 -6 -7 2925.64 205.712 2 0 6 7 3034.21 161.463 3 0 6 8 25.1302 23.5000 2 0 6 8 8.74265 11.0680 3 0 6 9 1210.19 113.944 3 0 6 9 1178.41 131.622 2 0 6 10 898.264 103.086 3 0 6 10 808.431 113.716 2 0 6 11 3128.81 235.302 2 0 6 11 3005.77 199.649 3 0 -6 -11 3137.06 250.101 2 0 6 12 159.700 55.9984 2 0 6 12 143.385 42.7191 3 0 -6 -12 207.690 73.7244 2 0 6 -13 528.407 106.141 3 0 6 13 585.083 112.632 2 0 -6 -13 505.643 108.452 2 0 6 -13 463.851 59.2630 1 0 6 13 460.001 82.5801 3 0 -6 -14 8456.47 451.078 2 0 6 14 8322.21 433.384 2 0 6 14 8241.85 375.120 3 0 6 -14 8528.04 431.496 3 0 6 -14 7496.73 184.415 1 0 6 -15 196.138 92.2383 3 0 6 15 76.3777 52.8974 2 0 6 15 52.1082 43.0513 3 0 -6 -15 161.449 91.1173 2 0 -6 -15 68.9938 43.2715 3 0 6 -16 2533.44 249.708 3 0 -6 -16 2453.46 203.268 3 0 6 16 2477.33 222.819 3 0 6 -17 55.0229 56.5740 3 0 6 17 22.8929 29.5980 3 0 -6 -17 29.6257 43.2605 3 0 6 -18 622.010 139.107 3 0 6 18 477.116 111.483 3 0 -6 -18 649.109 113.074 3 0 6 -19 722.284 149.092 3 0 -6 -19 809.094 133.595 3 0 6 19 572.423 123.736 3 0 -6 -20 360.926 86.8530 3 0 6 -20 318.165 98.2723 3 0 -6 -21 113.343 53.5789 3 0 6 -21 120.867 67.3620 3 0 -6 -22 198.165 73.3073 3 0 6 -22 121.834 68.0841 3 0 -6 -23 63.2032 58.7822 3 0 6 -23 31.7470 28.7696 3 0 -6 -24 49.1567 40.5247 3 0 6 -24 83.2258 51.6194 3 0 6 -25 81.2150 70.7345 3 0 -6 -25 72.1373 41.4517 3 0 6 -26 56.6295 64.4498 3 0 -6 -26 20.6229 22.2332 3 0 -6 -27 2.25179 29.3567 3 0 -6 -28 65.4084 48.9931 3 0 -6 -29 138.164 81.1382 3 0 -7 0 62.2550 26.0478 2 0 7 0 2.15526 16.4503 2 0 7 -1 756.784 103.143 2 0 -7 -1 692.507 83.5362 2 0 7 1 825.912 96.2339 2 0 -7 1 732.567 86.7477 2 0 -7 -2-1.92268 21.9338 2 0 -7 2 31.6263 20.6424 2 0 7 2 7.81192 12.1486 2 0 -7 -3 171.600 48.8250 2 0 -7 3 69.9902 29.7617 2 0 7 3 158.457 43.7218 2 0 -7 4 1299.01 124.945 2 0 -7 -4 1511.67 135.474 2 0 7 4 1506.96 128.520 2 0 -7 5 884.551 112.481 2 0 -7 -5 1047.16 117.096 2 0 7 5 1073.82 110.995 2 0 -7 -6-34.9613 32.1422 2 0 7 6-3.98018 15.3465 2 0 7 7 485.148 68.5465 3 0 7 7 457.705 77.7816 2 0 7 8 2040.24 173.055 2 0 7 8 2045.72 146.590 3 0 7 9-21.1398 28.0413 3 0 7 9 46.3899 30.0102 2 0 -7 -10 471.901 98.4265 2 0 7 10 380.855 83.5529 2 0 7 10 323.482 65.7989 3 0 7 11 4675.11 252.355 3 0 -7 -11 4765.06 315.934 2 0 7 11 4687.93 293.012 2 0 -7 -12 744.646 131.572 2 0 7 12 701.110 103.244 3 0 7 12 751.383 126.046 2 0 7 13 42.8322 27.5296 3 0 7 13 64.4532 52.5620 2 0 -7 -13 101.655 58.8308 2 0 7 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419.531 129.901 3 0 -11 -17 409.099 128.370 2 0 -11 -18 384.804 125.733 2 0 11 -18 489.303 138.645 3 0 11 -19 66.2851 57.3832 3 0 11 -20-12.7364 33.8384 3 0 11 -21 68.3969 77.9426 3 0 11 -22 133.557 90.8922 3 0 -12 0 1869.37 169.319 2 0 12 0 413.618 97.7932 2 0 -12 -1 80.3798 17.1304 2 0 -12 1 109.256 26.1893 2 0 12 1 236.797 85.3543 2 0 -12 -2 358.944 70.7778 2 0 -12 2 546.452 93.6948 2 0 12 2 483.209 102.590 2 0 -12 3 1639.58 162.781 2 0 12 3 628.465 115.565 2 0 -12 -4 1958.93 189.463 2 0 -12 4 1695.10 171.940 2 0 12 4 1764.57 191.057 2 0 -12 5 1060.55 136.308 2 0 12 5 1052.70 149.244 2 0 -12 -5 977.354 140.327 2 0 -12 -6 249.706 70.5082 2 0 -12 6 263.612 69.3730 2 0 12 6 168.200 60.3440 2 0 -12 -7-20.3343 48.0365 2 0 -12 7 36.4367 36.2634 2 0 12 7 14.2653 21.4571 2 0 12 8 20.2402 17.8614 2 0 -12 8 19.2279 22.9731 2 0 12 8 4.47338 21.0771 3 0 -12 -8 39.6725 29.3250 2 0 -12 9 525.604 107.595 2 0 -12 -9 527.349 115.583 2 0 12 9 482.480 105.612 2 0 12 9 543.903 103.868 3 0 12 10 783.396 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26.8602 63.8635 2 0 14 -16 125.204 89.0311 3 0 -14 16-45.0762 43.9434 2 0 -14 -17 3.59327 37.6046 2 0 -14 17 0.10807 33.7803 2 0 14 -17 46.3950 61.9298 3 0 -14 -18 7.52188 32.3313 2 0 -14 18-14.8299 34.0026 2 0 14 -18 45.6936 44.6497 3 0 -14 -19 0.14370 34.6857 2 0 14 -19 55.6840 52.3663 3 0 -14 19 0.48708 35.4209 2 0 -14 20 14.7149 59.4498 2 0 -14 21 0.13058 33.1936 2 0 -15 0 859.252 127.248 2 0 -15 -1-29.1912 28.7712 2 0 -15 1-22.2562 31.2088 2 0 -15 2-7.43458 19.5401 2 0 -15 -2 92.4478 50.9934 2 0 -15 -3 623.578 138.996 2 0 -15 3 322.177 85.5848 2 0 -15 -4 1115.85 182.102 2 0 -15 4 563.451 107.681 2 0 -15 5-2.24687 17.9076 2 0 -15 -5 79.2965 51.3243 2 0 -15 6-4.54926 18.5353 2 0 -15 -6 29.0677 31.1510 2 0 -15 -7-31.8017 37.1070 2 0 -15 7-21.9913 27.7008 2 0 -15 -8-43.6980 39.0697 2 0 -15 8-0.07346 50.1337 2 0 -15 9 32.8610 23.0678 2 0 -15 -9 15.7042 29.8254 2 0 -15 10 33.2861 37.5009 2 0 -15 -10 26.7469 30.7010 2 0 -15 11 21.1081 36.9734 2 0 -15 -11 19.5481 31.4630 2 0 -15 -12 102.196 64.5572 2 0 -15 12 26.0129 26.9509 2 0 -15 -13 159.501 84.0972 2 0 -15 13 112.806 71.0601 2 0 -15 -14 57.0098 61.5970 2 0 -15 14 44.4841 47.2469 2 0 -15 15 65.9923 51.0138 2 0 -15 -15 179.573 110.762 2 0 -15 16 48.7575 59.7112 2 0 15 -16 132.320 99.0167 3 0 -15 -16 40.4440 58.7768 2 0 -15 17 7.64712 38.2755 2 0 -15 -17 47.8830 74.3771 2 0 15 -17 159.260 99.6480 3 0 -15 -18 19.4729 48.4095 2 0 -15 18-41.4611 44.0102 2 0 15 -18 41.8973 70.0564 3 0 -15 -19-49.7864 53.4967 2 0 -15 19 4.22267 27.2184 2 0 -15 20 0.12517 29.3534 2 0 -15 21 7.96624 54.8778 2 0 -16 0 558.092 106.902 2 0 -16 1-114.852 51.9725 2 0 -16 -1 121.852 60.1774 2 0 -16 2-10.8285 17.6129 2 0 -16 -2 87.8351 47.9729 2 0 -16 3 328.898 86.0937 2 0 -16 -3 480.763 112.773 2 0 -16 4 461.543 106.774 2 0 -16 -4 816.446 148.240 2 0 -16 -5 37.9273 32.9083 2 0 -16 5 20.8875 43.0652 2 0 -16 -6 172.318 71.6295 2 0 -16 6 91.2250 48.2556 2 0 -16 7 29.3069 37.9409 2 0 -16 -7-23.0750 27.0269 2 0 -16 8-14.8261 25.9056 2 0 -16 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771.466 125.193 3 -2 2 -16 826.821 136.659 3 2 -2 17 854.108 118.638 1 -2 2 -17 893.413 149.820 3 -2 -2 -17 876.882 139.738 3 -2 2 -18 251.638 78.9618 3 -2 -2 -18 330.217 94.6346 3 -2 -2 -19 6.73216 26.8736 3 -2 2 -19-96.9405 53.4315 3 -2 2 -20 21.1808 40.8284 3 -2 -2 -20 70.9433 45.4921 3 -2 -2 -21 103.341 62.6182 3 -2 2 -21-7.37779 31.2218 3 -2 2 -22 327.543 104.292 3 -2 -2 -22 263.852 100.773 3 -2 -2 -23 64.3847 51.2755 3 -2 2 -23 104.146 66.5498 3 -2 -2 -24 40.5449 49.3607 3 -2 2 -24 18.9961 35.7258 3 -2 2 -25 19.3734 34.3507 3 -2 -2 -25 49.8328 43.5254 3 -2 2 -26-55.6382 50.0425 3 -2 -2 -26 3.16337 34.0491 3 -2 -2 -27 6.76204 23.6544 3 2 -3 -30-3.30042 42.4347 3 2 3 -29 26.2774 24.2945 3 2 -3 -29 25.6663 43.4904 3 2 -3 -28 1.13619 45.7364 3 2 3 -28 2.08394 33.1516 3 2 3 -27 117.093 77.3349 3 2 -3 -27 117.976 64.1120 3 2 -3 -26 16.4477 32.7943 3 2 3 -26 10.7382 23.3215 3 2 3 -25 217.558 103.275 3 2 -3 -25 245.071 90.3807 3 2 3 -24 164.205 80.1336 3 2 -3 -24 220.208 75.3863 3 2 3 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2 -2 3 13 6105.29 332.937 1 -2 -3 12 2497.74 199.012 2 -2 3 12 2473.87 212.261 1 2 -3 -12 2482.71 150.654 3 -2 3 12 2581.77 213.001 2 2 3 -12 2660.46 138.892 1 -2 3 11 124.962 55.0169 2 2 3 -11 146.759 33.9391 1 2 -3 -11 111.939 35.5509 3 -2 -3 11 78.2614 34.0431 2 -2 3 11 123.358 47.1047 1 -2 -3 10 10409.5 367.542 2 -2 3 10 10627.9 432.487 1 -2 3 10 10599.3 400.483 2 2 -3 -10 10260.5 265.794 3 2 -3 -9 5328.54 177.456 3 -2 3 9 5132.59 298.016 1 -2 3 9 5376.31 277.668 2 -2 -3 9 4822.86 240.457 2 -2 3 8 10384.8 419.483 1 -2 -3 8 10010.4 318.881 2 -2 3 8 10623.9 374.433 2 2 -3 -8 10331.1 218.678 3 -2 3 7 447.762 72.3344 2 -2 3 7 414.434 83.6810 1 -2 -3 7 482.433 65.4097 2 2 -3 -7 465.080 41.8509 3 -2 3 6 1027.86 108.821 2 -2 3 6 1022.92 127.042 1 -2 -3 6 1043.47 87.2455 2 2 -3 -6 991.136 52.9305 3 -2 -3 5 43.4483 13.1795 2 -2 3 5 43.0215 22.6591 2 -2 3 4 1109.83 108.217 2 -2 -3 4 1134.83 65.9939 2 -2 -3 3 6654.25 132.838 2 -2 3 3 7213.16 282.866 2 2 -3 -3 6692.26 119.568 3 2 -3 -2 203.974 24.5047 3 -2 3 2 174.667 35.2189 2 -2 3 1 1499.18 133.022 2 2 -3 -1 1646.77 81.3702 3 -2 3 1 1504.55 74.3900 3 2 -3 0 1867.55 99.8201 3 -2 3 0 1830.91 92.2465 3 -2 3 0 1863.18 152.099 2 -2 3 -1 23300.6 578.337 2 2 -3 1 22622.5 380.798 3 -2 3 -1 22640.6 364.877 3 -2 3 -2 469.324 58.8396 3 2 -3 2 512.603 63.8848 3 2 -3 3 17.8042 15.2462 3 -2 3 -3 48.7768 27.5929 3 2 -3 3-13.3039 26.3708 1 2 -3 4 2723.32 169.365 3 2 -3 4 2738.36 204.968 1 2 3 4 2642.44 170.004 3 -2 3 -4 2746.25 159.248 3 -2 3 -4 2980.25 181.682 1 -2 3 -5 822.783 93.5950 1 2 -3 5 753.544 106.873 1 2 -3 5 718.932 92.1869 3 2 3 5 701.892 91.8160 3 -2 3 -5 697.990 87.5739 3 2 3 6 1293.16 126.533 3 2 -3 6 1297.11 140.899 1 -2 3 -6 1394.24 128.852 3 2 -3 6 1347.09 131.056 3 2 -3 7 3951.31 249.081 1 -2 3 -7 3670.82 214.453 3 2 3 7 3648.33 220.219 3 2 -3 7 3737.62 232.349 3 2 -3 8 463.399 87.0671 3 2 3 8 472.461 83.8255 2 2 3 8 404.550 74.2501 3 2 -3 8 395.447 77.2649 1 2 -3 9 1139.73 137.967 3 2 3 9 1190.53 138.544 2 2 -3 9 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129.128 62.3514 3 2 -4 -19 118.674 47.6426 3 2 -4 -18 55.2339 50.9065 2 2 4 -18 18.8372 33.7177 3 -2 4 18-53.1858 45.3183 1 2 -4 -17-4.17114 29.2519 2 -2 4 17 17.5579 27.2688 1 -2 -4 17 49.3615 35.3637 2 2 -4 -16 241.393 81.8318 2 -2 -4 16 165.261 69.8090 2 -2 -4 15 516.135 108.303 2 -2 4 15 599.391 120.425 2 2 -4 -15 436.721 73.0891 3 2 -4 -15 467.832 113.005 2 -2 4 14 219.070 74.8561 2 2 4 -14 134.674 28.1713 1 2 -4 -14 218.529 48.9777 3 2 -4 -14 206.434 74.5502 2 -2 -4 14 199.236 63.4350 2 2 -4 -13 614.711 119.279 2 -2 -4 13 632.415 107.256 2 2 4 -13 623.191 62.7418 1 -2 4 13 576.351 110.372 2 2 -4 -13 556.984 73.0686 3 -2 4 12 28.7407 32.8651 2 2 -4 -12 49.4805 24.8531 3 -2 -4 12 13.4799 18.5028 2 -2 -4 11 2161.11 177.909 2 2 -4 -11 2145.13 119.999 3 -2 4 11 2410.53 205.040 2 -2 -4 10 3138.27 203.324 2 -2 4 10 2964.65 217.742 2 2 -4 -10 2833.43 125.025 3 -2 -4 9 1703.00 139.801 2 -2 4 9 1553.23 154.593 2 2 -4 -9 1484.50 80.5424 3 -2 -4 8 522.696 73.5865 2 -2 4 8 610.372 96.8765 2 2 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145.879 3 -2 4 -6 1747.03 144.528 3 2 4 6 1664.48 133.758 2 -2 4 -7 142.145 45.2713 1 2 -4 7 71.7066 25.6464 3 -2 4 -7 97.9737 42.5502 3 2 4 7 112.241 39.5879 2 2 4 7 105.556 42.4814 3 2 4 8 1528.43 147.241 2 -2 4 -8 1483.15 150.931 3 2 4 8 1459.33 147.071 3 2 -4 8 1477.01 150.867 3 2 4 9 10134.8 402.955 2 -2 4 -9 9948.08 389.605 3 2 -4 9 9813.83 408.298 3 2 4 9 10159.2 407.217 3 2 4 10 4483.63 279.554 3 -2 4 -10 4518.01 273.638 3 2 4 10 4342.66 273.331 2 2 -4 10 4305.08 286.130 3 -2 4 -11 179.851 68.6474 3 2 4 11 56.9597 43.0841 3 2 4 11 44.9771 38.8757 2 -2 4 -12 1874.52 188.209 3 2 4 12 2018.53 205.233 2 2 4 12 2158.08 207.050 3 2 4 13 363.774 92.0974 3 -2 4 -13 435.856 102.588 3 2 4 13 377.751 91.1563 2 -2 -4 -13 402.433 91.3612 3 -2 -4 -14 69.0593 46.5181 3 -2 4 -14 27.1505 30.3048 3 2 4 14-3.72684 44.6611 3 2 4 14 60.6784 50.9028 2 2 4 15 517.031 121.108 2 -2 4 -15 491.442 107.555 3 -2 -4 -15 541.503 102.720 3 -2 -4 -16 14.1769 28.3088 3 -2 4 -16 20.3709 17.8804 3 -2 -4 -17 149.439 60.8953 3 -2 4 -17 133.427 58.1878 3 -2 4 -18 27.6614 26.2400 3 -2 -4 -18 24.3047 41.2261 3 -2 4 -19 7.03438 41.4100 3 -2 -4 -19-58.0777 47.2662 3 -2 4 -20 61.4863 62.7515 3 -2 -4 -20-16.4302 20.5498 3 -2 -4 -21 808.786 154.026 3 -2 4 -21 694.149 150.476 3 -2 4 -22 804.072 168.129 3 -2 -4 -22 802.879 160.422 3 -2 4 -23 178.725 84.6026 3 -2 -4 -23 172.820 91.4212 3 -2 -4 -24-9.38815 30.3429 3 -2 4 -24 33.9995 40.2507 3 -2 4 -25 59.0500 55.4894 3 -2 -4 -25 85.7536 57.2074 3 -2 -4 -26 37.3286 39.2381 3 -2 -4 -27 8.89650 36.7422 3 2 5 -28 7.86442 51.8971 3 2 5 -27 0.76711 42.5973 3 2 -5 -27 38.7234 37.9248 3 2 5 -26 158.387 90.4074 3 2 -5 -26 143.010 66.4115 3 2 5 -25 224.470 98.6058 3 2 -5 -25 167.438 58.8958 3 2 5 -24 44.1072 22.7179 3 2 -5 -24-26.1959 30.9758 3 2 -5 -23 3.77028 18.6446 3 2 5 -23 20.0487 47.3257 3 2 5 -22 70.7876 31.1916 3 2 -5 -22-8.59513 23.3959 3 2 -5 -21 22.5117 19.5367 3 -2 5 21-12.6663 34.5783 1 2 5 -20 104.530 60.4739 3 2 -5 -20 82.7875 61.6600 2 -2 5 20 84.3976 52.5960 1 2 -5 -20 127.753 47.8366 3 2 -5 -19 407.543 118.873 2 2 5 -19 286.025 90.1179 3 2 -5 -19 339.632 70.6863 3 2 -5 -18 293.335 107.563 2 2 -5 -17 12.4940 31.2370 2 -2 -5 17 36.5788 39.4159 2 2 -5 -16 193.993 49.0919 3 2 -5 -16 245.802 89.4269 2 -2 -5 16 155.517 62.8865 2 -2 -5 15 328.552 89.0796 2 2 -5 -15 303.216 56.1442 3 2 5 -15 328.861 44.5527 1 2 -5 -15 343.162 100.775 2 -2 5 14 144.967 59.7199 2 2 -5 -14 100.409 29.8710 3 2 -5 -14 88.0813 49.1924 2 -2 -5 14 120.011 44.3920 2 2 -5 -13 767.101 78.2680 3 -2 -5 13 762.746 119.543 2 -2 5 13 1001.60 146.998 2 2 -5 -13 876.081 139.652 2 -2 5 12 254.649 71.0846 2 2 -5 -12 296.505 43.9962 3 -2 -5 12 271.377 65.0227 2 -2 -5 11 534.426 90.1735 2 -2 5 11 499.732 94.4597 2 2 -5 -11 485.866 52.6014 3 2 -5 -10 33.1472 16.4836 3 -2 5 10-9.70245 27.6599 2 -2 -5 10 57.2754 33.1788 2 -2 5 9 1480.34 153.816 2 -2 -5 9 1459.60 129.465 2 -2 -5 8 818.475 89.6214 2 -2 5 8 750.510 108.911 2 -2 -5 7 3035.61 159.769 2 -2 5 7 2842.09 205.788 2 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41.1907 1 2 5 9 76.3450 38.5406 3 2 5 9 80.3901 35.2417 2 -2 5 -9 89.4451 41.0769 3 2 5 10 3148.81 230.723 2 -2 5 -10 3182.80 233.385 3 2 5 10 3280.11 241.589 3 2 5 11 155.571 54.5018 3 -2 5 -11 277.232 79.2412 3 2 5 11 204.928 65.3429 2 2 5 12 176.063 63.5583 3 2 5 12 115.384 50.2831 2 -2 5 -12 157.913 59.9674 3 2 5 13 1058.85 152.364 2 -2 5 -13 932.534 141.899 3 2 5 13 1196.05 163.694 3 2 5 14 3124.14 275.138 2 -2 5 -14 3093.11 263.367 3 -2 5 -15 214.130 74.3815 3 2 5 15 58.5283 54.1084 2 -2 5 -16-10.1776 23.3796 3 -2 5 -17 197.572 75.8628 3 -2 5 -18-19.7234 46.8397 3 -2 5 -19-30.9265 48.6737 3 -2 -5 -19-23.1285 30.3599 3 -2 5 -20 66.2545 55.9212 3 -2 -5 -20 59.0335 50.0659 3 -2 5 -21 89.0323 68.6753 3 -2 -5 -21 44.9836 45.5816 3 -2 -5 -22 667.300 150.382 3 -2 5 -22 568.321 146.819 3 -2 5 -23 131.611 81.4857 3 -2 -5 -23 103.431 63.8653 3 -2 -5 -24 145.488 78.4023 3 -2 5 -24 51.8721 43.4964 3 -2 5 -25 15.9526 29.1213 3 2 6 -27 18.2264 30.6951 3 2 6 -26 236.244 107.763 3 2 -6 -26 187.384 70.3330 3 2 -6 -25 62.8248 36.3227 3 2 6 -25 112.708 80.0155 3 2 6 -24-80.6752 54.9059 3 2 -6 -24 14.5880 25.6962 3 2 6 -23 8.00739 20.0498 3 2 -6 -23 27.8736 27.1340 3 2 6 -22-21.3725 32.7070 3 2 -6 -22 32.5347 31.3129 3 2 -6 -21 616.657 157.003 2 2 6 -21 642.846 151.727 3 2 -6 -21 523.496 91.7697 3 2 6 -20 269.067 100.780 3 2 -6 -20 167.467 85.6098 2 2 -6 -20 232.899 59.6459 3 2 -6 -19 70.9763 72.6274 2 2 -6 -18 2731.38 305.541 2 2 -6 -17 1789.79 238.245 2 -2 -6 17 1380.05 188.861 2 2 -6 -16 3505.75 324.397 2 -2 -6 16 3066.51 271.812 2 2 -6 -16 3323.96 185.132 3 2 6 -16 2996.91 125.756 1 -2 -6 15 80.1151 45.9872 2 2 -6 -15 58.9301 25.3400 3 2 -6 -15 71.4042 54.6274 2 2 -6 -14 72.7719 25.3948 3 -2 -6 14 128.449 50.3310 2 2 -6 -14 46.3288 48.9128 2 -2 -6 13 763.860 122.102 2 -2 6 13 770.704 130.490 2 2 -6 -13 888.246 153.090 2 2 -6 -13 840.721 79.8512 3 -2 -6 12 867.760 120.677 2 -2 6 12 811.676 126.253 2 2 -6 -12 820.040 142.611 2 -2 -6 11 178.742 54.8517 2 -2 6 11 131.899 49.6943 2 -2 6 10 4961.48 297.865 2 -2 -6 10 4616.35 248.198 2 -2 -6 9 311.675 64.4793 2 -2 6 9 188.134 61.3976 2 -2 6 8 14170.3 484.014 2 -2 6 7 413.524 82.2268 2 -2 6 6 8455.56 359.852 2 -2 6 5 918.977 121.563 2 -2 6 4 4220.39 256.134 2 -2 -6 4 4679.63 139.484 2 -2 6 3 72.8636 32.9882 2 -2 -6 3 49.0517 11.1474 2 -2 6 3 66.8611 11.9334 3 -2 6 2 72.7345 35.3750 2 -2 6 2 93.8724 20.6635 3 -2 6 1 9686.86 416.959 2 -2 6 1 9919.07 220.273 3 -2 6 0 444.324 91.4157 2 -2 6 0 472.370 56.4178 3 2 6 1 964.037 54.5380 2 -2 6 -1 831.998 79.2067 3 -2 6 -1 745.886 122.759 2 2 6 2 628.697 50.8014 2 -2 6 -2 838.559 93.1669 3 -2 6 -3 20088.1 444.936 3 -2 6 -3 19627.7 633.123 1 2 6 3 20687.6 338.500 2 -2 6 -4 7309.12 284.622 3 -2 6 -4 7055.59 376.449 1 2 6 4 7048.19 225.741 2 -2 6 -5 2337.42 218.392 1 2 6 5 2541.14 151.425 2 -2 6 -5 2540.34 177.485 3 -2 6 -6 22.1761 19.1817 1 2 6 6-6.43589 19.6842 2 -2 6 -6 62.1306 38.2062 3 2 6 6 6.09076 14.1756 3 2 6 7 96.8813 36.0771 2 -2 6 -7 98.0535 39.8408 1 -2 6 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58.1326 3 2 -7 -24 56.3955 36.2490 3 2 7 -23 136.421 84.4693 3 2 -7 -23 58.0963 35.1603 3 2 7 -22 70.7000 62.7573 3 2 -7 -22 44.0046 52.5911 2 2 -7 -22 25.3683 12.7854 3 2 7 -21 211.919 88.7326 3 2 -7 -21 114.835 69.6594 2 2 -7 -21 171.255 56.2131 3 2 -7 -20 560.090 145.784 2 2 7 -20 441.358 117.334 3 2 -7 -19 184.058 78.9915 2 2 -7 -18 51.4837 62.6462 2 -2 -7 17-78.9586 50.5551 2 2 7 -17 18.6499 12.1123 1 2 -7 -17 46.8427 43.7831 2 -2 -7 16 22.7677 27.9263 2 2 -7 -16 58.2173 44.4397 2 2 -7 -15 373.384 105.566 2 -2 -7 15 343.401 87.5805 2 -2 -7 14 856.724 133.156 2 2 -7 -14 827.595 155.822 2 -2 -7 13 2259.50 208.381 2 2 -7 -13 2431.20 260.042 2 -2 7 12 603.259 116.411 2 -2 -7 12 662.568 108.681 2 2 -7 -12 835.550 151.726 2 -2 7 11 1010.12 143.311 2 2 -7 -11 1157.54 168.145 2 -2 7 10 526.092 106.119 2 2 -7 -10 542.066 110.399 2 -2 7 9 35.0364 20.3862 2 -2 7 8 1064.61 136.598 2 -2 7 7 48.7344 27.7894 2 -2 7 6 205.561 61.5344 2 -2 7 5 934.568 143.330 2 -2 -7 5 1055.49 80.5690 2 -2 7 4 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3 2 7 10 599.689 108.668 3 2 7 10 583.007 100.242 2 2 7 11 40.6715 28.1543 2 -2 7 -11 97.3945 48.7712 3 2 7 11 66.4625 33.6829 3 2 7 12 912.079 140.152 3 -2 7 -12 822.131 132.765 3 2 7 12 810.060 128.395 2 -2 7 -13 129.733 59.4352 3 2 7 13 208.932 68.7091 2 -2 7 -14-0.52152 23.0138 3 2 7 14 21.9047 35.7044 2 -2 7 -15 378.043 100.378 3 -2 7 -16 137.008 69.4838 3 -2 7 -17 962.102 167.607 3 -2 7 -18 97.2076 65.8426 3 -2 7 -19 548.080 133.980 3 -2 7 -20 190.531 86.6655 3 -2 7 -21-20.3729 25.5049 3 -2 7 -22 39.1958 61.6801 3 -2 7 -23 78.2916 68.6958 3 -2 7 -24 65.5254 71.7444 3 2 8 -25 5.78135 39.0912 3 2 8 -24-18.6481 35.5842 3 2 -8 -23 148.668 91.5460 2 2 8 -23 218.342 95.4792 3 2 8 -22 23.2288 24.4758 3 2 -8 -22 47.0293 58.9715 2 2 -8 -21-14.5773 46.2862 2 2 8 -21 71.9969 44.9363 3 2 -8 -20 4.97217 33.5357 2 2 -8 -19 148.501 77.1037 2 2 8 -18 195.757 30.9065 1 2 -8 -18 248.804 96.3234 2 -2 -8 17-9.64619 34.8257 2 2 -8 -17 58.2154 44.7868 2 -2 -8 16-8.79338 34.5793 2 2 -8 -16-34.0624 29.1411 2 -2 -8 15 129.888 52.0203 2 2 -8 -15 192.554 87.9536 2 2 -8 -14 854.346 164.338 2 2 -8 -13 830.780 154.351 2 2 -8 -12 208.173 75.8265 2 2 -8 -11-9.71084 32.7502 2 2 -8 -10 9.52365 27.2139 2 -2 8 10 6.20867 24.1080 2 2 -8 -9 73.4672 41.7193 2 -2 8 9 112.745 53.3817 2 2 -8 -8 2978.56 254.857 2 -2 8 8 2942.37 236.215 2 2 -8 -7 54.4582 37.0326 2 -2 8 7 55.3847 33.8368 2 -2 8 6 344.276 81.6139 2 -2 -8 6 330.807 51.8985 2 -2 8 5 6.11224 5.68629 3 -2 -8 5-10.1809 11.2281 2 -2 8 5-5.83226 25.0500 2 -2 8 5 4.43065 5.42040 3 -2 -8 4 690.990 59.8525 2 -2 8 4 638.546 116.624 2 -2 8 4 562.410 46.0688 3 -2 8 3 85.9040 21.4197 3 -2 8 3 31.3877 36.3519 2 -2 -8 3 86.3940 18.5666 2 -2 -8 2 912.011 63.0596 2 -2 8 2 946.058 75.1280 3 -2 8 2 997.347 146.576 2 -2 -8 1 744.877 58.5034 2 -2 8 1 761.782 72.6952 3 -2 8 1 579.088 113.058 2 -2 -8 0 147.320 26.2259 2 -2 8 0 177.675 64.9187 2 -2 8 0 160.696 36.5985 3 -2 8 -1 792.864 87.1778 3 -2 -8 -1 774.151 69.3667 2 -2 8 -1 766.869 136.258 2 2 8 1 864.858 67.4789 2 2 8 2 2034.76 112.045 2 -2 8 -2 1820.61 142.099 3 -2 -8 -2 1803.71 117.523 2 2 8 3 12195.9 291.208 2 -2 -8 -3 11784.0 329.984 2 -2 8 -3 11642.6 367.430 3 -2 -8 -4 181.807 52.6290 2 -2 8 -4 319.315 80.9170 3 2 -8 4 366.226 107.279 2 2 8 4 112.720 32.0056 2 2 -8 5 5621.15 352.146 2 -2 8 -5 5802.92 286.544 3 2 8 5 5786.64 235.976 2 -2 -8 -5 5766.52 263.899 2 2 -8 6 694.276 123.964 2 2 8 6 794.060 93.0190 2 -2 8 -6 914.630 121.557 3 2 -8 7-29.3254 37.7948 2 -2 8 -7 110.203 51.5823 3 2 8 7 101.149 48.4572 3 2 8 7 88.9069 38.0141 2 2 8 8 2891.53 231.997 3 2 8 8 2846.91 198.787 2 -2 8 -8 2671.11 217.566 3 2 -8 8 2624.34 261.655 2 2 8 9 2778.79 207.792 2 2 -8 9 2288.88 246.249 2 2 8 9 2884.61 236.959 3 -2 8 -9 2613.67 222.724 3 2 8 10 484.044 93.4980 3 2 8 10 575.534 98.7746 2 -2 8 -10 489.860 102.351 3 2 8 11 119.005 50.7744 2 -2 8 -11 159.603 63.5835 3 2 8 11 69.5401 36.4836 3 -2 8 -12 2192.99 225.487 3 2 8 12 2138.40 211.631 2 -2 8 -13 40.1913 48.7357 3 2 8 13 43.1549 32.1101 2 2 8 14 13.1029 33.1168 2 -2 8 -14-35.0515 38.6787 3 -2 8 -15 62.4667 49.1901 3 -2 8 -16 34.3732 43.9000 3 -2 8 -17 45.6804 39.2034 3 -2 8 -18 41.5591 48.1334 3 -2 8 -19 28.1462 47.3609 3 -2 8 -20 374.333 117.417 3 -2 8 -21 9.79713 43.6940 3 -2 8 -22 141.392 66.1962 3 -2 8 -23 394.227 133.426 3 2 9 -24 115.590 77.4867 3 2 9 -23 116.683 75.8204 3 2 -9 -23 31.1436 62.4454 2 2 9 -22 214.237 100.266 3 2 -9 -22 194.298 121.390 2 2 9 -21-8.27161 29.9411 3 2 -9 -21 56.0318 53.6117 2 2 -9 -20 205.187 97.7836 2 2 -9 -19 23.8872 63.8152 2 2 -9 -18 63.0978 56.0521 2 2 -9 -17 55.6829 46.1284 2 -2 -9 16-10.5373 25.2490 2 2 -9 -16 69.1779 62.7801 2 2 -9 -15 15.5244 25.0273 2 2 -9 -14 55.0557 59.0922 2 2 -9 -13 88.2245 54.8405 2 2 -9 -12 146.377 64.9198 2 2 -9 -11 103.834 48.6908 2 2 -9 -10 2697.30 264.396 2 -2 9 9 7.62186 6.02535 3 2 -9 -9-6.92732 29.6861 2 -2 9 9 4.63876 14.6786 2 2 -9 -8 31.4545 30.1944 2 -2 9 8 60.1546 44.4366 2 2 -9 -7 1305.19 172.807 2 -2 9 7 1433.32 171.473 2 -2 -9 7 1248.09 115.024 2 -2 -9 6 1079.13 97.8770 2 2 -9 -6 1064.34 148.409 2 -2 9 6 1051.96 145.408 2 -2 9 6 791.758 52.2927 3 -2 -9 5 35.4490 19.1840 2 -2 9 5 66.4111 39.7027 2 2 -9 -5 8.50754 33.9568 2 -2 9 4 235.634 66.9214 2 -2 -9 4 201.432 35.2108 2 2 -9 -4 205.677 57.8392 2 -2 -9 3 183.131 30.6278 2 2 -9 -3 165.592 62.4284 2 -2 9 2 4014.62 310.041 2 2 -9 -2 3384.98 255.056 2 -2 -9 2 2908.23 128.227 2 2 -9 -1 4849.20 301.069 2 -2 -9 1 4607.12 166.753 2 -2 9 1 4599.67 196.714 3 -2 9 1 4847.49 334.219 2 -2 9 0 1391.38 118.154 3 2 -9 0 1464.45 169.787 2 -2 -9 0 1239.78 87.3587 2 -2 9 0 1362.87 185.140 2 -2 -9 -1 816.154 75.6609 2 -2 9 -1 761.364 140.694 2 2 -9 1 608.546 109.171 2 -2 9 -1 748.909 91.0942 3 2 9 1 812.237 76.2701 2 2 9 2 925.470 83.2096 2 2 -9 2 892.307 141.916 2 -2 9 -2 808.962 97.3481 3 -2 -9 -2 884.668 86.6101 2 2 -9 3 1203.23 161.370 2 2 9 3 1178.50 99.7803 2 -2 -9 -3 1110.64 106.935 2 -2 9 -3 1148.84 122.339 3 -2 -9 -4-4.79295 11.3286 2 2 9 4 24.1605 23.0013 2 -2 9 -4 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151.302 72.8149 3 -2 9 -17 2.13623 24.9820 3 -2 9 -18-1.82670 35.5751 3 -2 9 -19 60.6793 47.3690 3 -2 9 -20 104.034 67.0866 3 -2 9 -21 80.7866 65.7517 3 -2 9 -22 175.348 88.1508 3 -2 9 -23 87.2699 84.3435 3 2 10 -23 11.7036 62.9718 3 2 -10 -23 45.2817 54.1570 2 2 10 -22 133.905 99.6913 3 2 -10 -22 70.6910 87.4283 2 2 -10 -21 38.6157 100.278 2 2 -10 -20-16.7273 36.3208 2 2 -10 -19 191.227 87.1222 2 2 -10 -18-21.4186 45.0634 2 2 -10 -17 167.342 94.1225 2 2 -10 -16 487.244 136.617 2 2 -10 -15 538.822 145.295 2 2 -10 -14 1504.08 228.041 2 2 -10 -13 165.295 76.3039 2 2 -10 -12 168.822 72.6221 2 -2 10 11 6.50357 6.94855 3 2 -10 -11-5.70403 33.8639 2 2 -10 -10 298.961 99.8079 2 -2 10 10 188.983 27.2374 3 -2 10 9 988.033 59.2741 3 2 -10 -9 1382.93 190.498 2 -2 -10 9 1240.65 140.112 2 -2 -10 8 47.1084 34.4824 2 2 -10 -8 29.7800 24.1892 2 -2 10 8 18.1717 9.34310 3 -2 10 7-5.94550 35.9028 2 2 -10 -7 27.8916 28.0357 2 -2 -10 7 4.47843 15.0033 2 -2 10 7-0.67336 5.16911 3 -2 -10 6-12.7330 14.5535 2 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224.192 1 3 -6 -8 1819.62 195.370 2 -3 -6 8 1548.44 112.606 2 -3 6 7 8055.98 390.664 2 -3 6 7 7628.78 464.919 1 -3 -6 7 7531.53 215.592 2 -3 6 6 953.968 138.851 2 -3 6 6 1000.43 170.169 1 -3 -6 6 1011.24 64.2308 2 -3 6 5 252.304 67.0467 2 -3 6 4 1190.99 154.989 2 -3 6 3 326.805 79.2900 2 -3 6 2 75.9823 118.686 2 -3 6 1 5055.15 170.371 3 -3 6 1 6180.16 388.998 2 -3 6 0 7439.92 228.502 3 -3 6 0 7966.29 443.433 2 -3 6 -1 648.942 73.9296 3 3 6 2 264.545 29.9811 2 -3 6 -2 271.516 51.0365 3 -3 6 -2 337.360 86.1063 1 -3 6 -3 2006.59 154.228 3 3 6 3 1844.71 101.798 2 -3 6 -3 1210.37 165.744 1 -3 6 -4 951.150 141.339 1 3 6 4 917.950 81.6361 2 -3 6 -4 837.444 100.617 3 3 6 5 141.254 32.7113 2 -3 6 -5 118.687 50.5144 1 -3 6 -5 184.470 48.5447 3 -3 6 -6 674.094 102.198 3 -3 6 -6 772.171 122.279 1 3 6 6 766.807 123.494 3 3 6 6 700.062 88.4285 2 3 -6 7 99.0114 56.3243 2 3 6 7 167.242 46.2745 2 -3 6 -7 206.806 61.9219 3 -3 6 -7 169.461 61.9134 1 3 6 7 165.279 49.8615 3 3 -6 8 349.179 96.7215 2 -3 6 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34.6827 39.6167 2 3 -7 -18 12.2322 43.4174 2 3 7 -18 22.1157 20.1303 1 3 7 -17 60.0201 31.1689 1 3 -7 -17 13.4266 37.8946 2 -3 -7 17 26.7306 28.5389 2 -3 -7 16 52.8546 35.6022 2 3 -7 -16-32.1283 54.0919 2 -3 7 16-21.9766 62.7592 1 -3 -7 15 245.994 68.8279 2 3 -7 -15 326.805 105.474 2 -3 7 15 196.661 83.6137 1 3 -7 -14 3880.76 347.392 2 -3 -7 14 3459.44 253.851 2 3 -7 -13 3823.09 336.326 2 -3 -7 13 3748.71 252.613 2 -3 -7 12 342.903 72.7400 2 3 -7 -12 249.603 79.8163 2 3 -7 -11 81.8031 41.5890 2 -3 -7 11 132.072 44.0919 2 3 -7 -10 91.5503 48.3779 2 -3 -7 10 80.1322 30.9104 2 3 -7 -9 195.730 75.8512 2 -3 -7 9 179.699 43.7608 2 -3 7 9 165.192 58.0686 2 3 -7 -8 363.216 102.349 2 -3 -7 8 185.550 39.3854 2 -3 7 8 258.652 81.3779 2 -3 7 7 4234.85 298.526 2 3 -7 -7 4357.31 304.729 2 -3 -7 7 3674.47 148.115 2 -3 7 6 582.701 118.110 2 -3 -7 6 495.559 41.9672 2 -3 7 5 243.570 71.4801 2 -3 7 4-38.6811 19.8797 2 -3 7 3 410.283 103.860 2 -3 7 2 847.159 155.294 2 -3 7 2 484.692 48.3000 3 -3 7 1 4146.11 156.541 3 -3 7 1 4483.23 331.281 2 -3 7 0 131.706 71.1601 2 -3 7 0 94.8686 27.4995 3 -3 7 -1 1233.30 181.228 1 -3 7 -1 1210.52 103.834 3 3 7 2 282.467 27.0621 2 -3 7 -2 196.070 71.8061 1 -3 7 -2 233.942 49.5155 3 3 7 3 292.998 35.6459 2 -3 7 -3 228.758 72.7351 1 -3 7 -3 279.188 58.0722 3 3 7 4 1596.52 101.755 2 -3 7 -4 1699.25 201.224 1 -3 7 -4 1532.63 140.658 3 3 7 5 5.23806 11.5399 2 3 -7 5 12.8781 33.7908 2 -3 7 -5 43.2341 26.6700 3 -3 7 -5-41.0428 31.4859 1 3 -7 6 81.2061 55.2130 2 -3 7 -6 58.4528 36.2160 1 3 7 6 20.6062 12.8167 2 -3 7 -6 51.8001 35.8750 3 3 7 6 39.8632 20.9781 3 -3 7 -7 1048.21 132.377 3 -3 7 -7 1091.87 154.216 1 3 7 7 996.085 109.213 2 3 7 7 1112.60 149.657 3 3 -7 7 994.017 158.978 2 3 -7 8 8.35095 36.3790 2 -3 7 -8 67.7964 42.8942 1 3 7 8 50.3117 21.5359 2 -3 7 -8 82.7635 42.7242 3 3 7 8 9.24317 25.8130 3 -3 7 -9 765.640 120.927 3 -3 7 -9 764.172 124.478 1 3 7 9 686.405 105.278 2 3 -7 9 805.703 160.441 2 3 -7 10 277.166 93.4165 2 3 7 10 192.619 61.6464 2 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77.2576 40.9522 1 -3 8 -11 53.8684 34.8509 3 3 -8 12-57.7469 57.7862 2 3 8 12-37.8965 35.6924 2 -3 8 -12 5.64519 26.5319 3 3 8 13-23.3124 37.0392 2 -3 8 -13-20.6796 37.0793 3 3 8 14-26.1343 31.4058 2 -3 8 -14 42.1742 34.6571 3 -3 8 -15 145.170 73.7000 3 -3 8 -16 238.199 88.0632 3 -3 8 -17 89.8536 66.3815 3 -3 8 -18 131.894 69.6582 3 -3 8 -19-2.76586 21.5214 3 -3 8 -20 20.4756 41.7078 3 -3 8 -21 0.11622 32.2880 3 -3 8 -22 53.6410 71.1662 3 3 9 -24 96.3967 91.6931 3 3 -9 -23 54.9059 77.0336 2 3 -9 -22 36.0454 55.8475 2 3 -9 -21 60.7979 33.4694 2 3 -9 -20 146.122 88.2208 2 3 -9 -19 6.06595 36.0673 2 3 -9 -18 3.45395 30.5205 2 3 -9 -17 732.229 177.371 2 -3 -9 17 435.136 103.090 2 3 -9 -16 366.974 122.269 2 -3 -9 16 228.495 67.4237 2 3 -9 -15 482.094 134.287 2 -3 -9 15 329.139 81.9782 2 3 -9 -14 275.584 106.049 2 -3 -9 14 212.736 64.3910 2 3 -9 -13-44.0574 58.5064 2 -3 -9 13 25.2797 21.6167 2 -3 -9 12 96.6415 38.5197 2 3 -9 -12 94.7351 69.1313 2 3 -9 -11 1152.22 186.873 2 -3 -9 11 1027.30 116.016 2 3 -9 -10-19.9843 30.8247 2 -3 -9 10-4.35782 11.2992 2 3 -9 -9 525.390 124.768 2 -3 -9 9 438.980 65.2965 2 3 -9 -8 72.7068 46.6655 2 -3 -9 8 39.6051 20.1294 2 -3 -9 8 75.4401 23.4407 2 -3 -9 7 1278.80 78.4539 2 3 -9 -7 1828.01 213.039 2 -3 -9 7 1318.38 88.7287 2 -3 -9 6 57.4236 13.9443 2 -3 -9 6 104.138 19.6593 2 3 -9 -6 172.862 74.1549 2 3 -9 -5 245.801 72.6952 2 3 -9 -4-48.1912 46.3953 2 -3 9 3 93.0174 51.6697 2 3 -9 -3 5.77204 34.4624 2 -3 9 3 31.7419 11.4373 3 -3 9 2 56.9288 46.4630 2 3 -9 -2 4.75257 31.9181 2 -3 9 2 8.61257 10.1743 3 -3 9 1 307.390 89.3447 2 -3 9 1 330.515 49.3905 3 3 -9 -1 467.864 106.148 2 -3 9 0 102.461 68.6536 2 3 -9 0 125.830 62.0493 2 -3 9 0 70.8624 27.6655 3 3 -9 1 695.999 130.991 2 -3 9 -1 760.732 156.329 1 -3 9 -1 726.314 86.9533 3 3 -9 2 559.127 133.770 2 -3 9 -2 374.957 70.6900 3 -3 9 -2 276.428 92.6597 1 3 9 2 292.404 30.9243 2 3 9 3 738.154 60.6626 2 3 -9 3 1055.00 171.047 2 3 9 4 426.816 53.0136 2 -3 9 -4 288.143 94.6607 1 3 -9 4 452.868 118.501 2 -3 9 -4 388.766 78.7219 3 3 -9 5 1086.91 174.616 2 3 9 5 1082.02 92.6632 2 -3 9 -5 850.974 161.593 1 -3 9 -5 952.821 123.800 3 -3 9 -6 530.080 121.933 1 3 -9 6 325.432 96.8997 2 3 9 6 585.486 75.0487 2 3 -9 7-36.7199 59.3487 2 -3 9 -7 67.8621 42.7688 1 -3 9 -7 71.8460 43.9897 3 3 9 7 102.734 30.7930 2 3 -9 8 815.248 149.488 2 3 9 8 1077.35 120.973 2 -3 9 -8 949.010 138.667 3 -3 9 -8 982.639 160.975 1 3 -9 9 210.675 73.0147 2 -3 9 -9 343.482 96.1960 1 -3 9 -9 524.700 108.698 3 3 9 9 451.843 83.0807 2 3 9 10 21.2340 25.3512 2 3 -9 10 0.09340 53.0888 2 -3 9 -10-11.8208 25.2940 3 -3 9 -10 82.3888 48.2230 1 3 -9 11 93.2351 48.8387 2 3 9 11 41.7821 34.6356 2 -3 9 -11 75.2906 43.5611 1 -3 9 -11 95.4457 43.5071 3 3 -9 12 9.84093 36.5586 2 3 9 12 84.9019 36.1160 2 -3 9 -12 108.039 53.9083 3 -3 9 -12 103.075 51.1592 1 3 -9 13 369.814 109.822 2 3 9 13 264.938 75.5511 2 -3 9 -13 392.336 105.535 3 3 -9 14 311.100 103.772 2 3 9 14 252.078 76.9934 2 -3 9 -14 338.750 98.7312 3 -3 9 -15 252.116 97.7312 3 -3 9 -16 358.187 109.850 3 -3 9 -17-19.5626 35.5340 3 -3 9 -18 69.7131 58.6948 3 -3 9 -19 27.3138 49.4298 3 -3 9 -20 40.5496 66.6440 3 -3 9 -21 138.341 92.1001 3 3 -10 -22 0.16321 55.7878 2 3 -10 -21 26.4574 41.1265 2 3 -10 -20-5.53110 29.3902 2 3 -10 -19 197.771 105.457 2 3 -10 -18 34.0428 40.4648 2 3 -10 -17 282.581 119.167 2 3 -10 -16 170.964 103.787 2 -3 -10 16 54.1633 42.8243 2 3 -10 -15 722.565 173.956 2 -3 -10 15 442.290 96.3728 2 3 -10 -14-103.020 68.8292 2 -3 -10 14 0.17464 25.2755 2 3 -10 -13 69.4521 56.7822 2 -3 -10 13 25.6944 16.8572 2 -3 -10 12 606.001 96.0774 2 3 -10 -12 818.550 166.484 2 3 -10 -11 105.236 67.1137 2 -3 -10 11 44.3554 18.3094 2 3 -10 -10 87.8437 49.4468 2 -3 -10 10 64.9820 22.4047 2 -3 -10 9 575.493 74.3310 2 3 -10 -9 721.473 144.752 2 -3 -10 9 648.275 78.3707 2 -3 -10 8 644.766 64.2756 2 -3 -10 8 671.323 74.2773 2 3 -10 -8 915.764 163.122 2 -3 -10 7 3262.95 141.516 2 -3 -10 7 3137.52 123.669 2 3 -10 -7 4270.29 336.844 2 -3 -10 6 89.5505 19.0873 2 -3 -10 6 72.3611 14.9668 2 3 -10 -6 264.240 98.4618 2 3 -10 -5 1084.12 165.698 2 3 -10 -4 157.265 61.9767 2 -3 10 3 495.550 47.1187 3 3 -10 -3 732.321 130.095 2 3 -10 -2 2124.24 229.597 2 -3 10 2 1583.01 100.903 3 3 -10 -1 2028.07 228.609 2 -3 10 1 1838.73 121.701 3 -3 10 0 415.286 62.1044 3 3 -10 0 440.316 103.660 2 3 -10 1-26.3143 42.5428 2 -3 10 -1-0.44199 10.8003 3 3 -10 2 113.579 84.8482 2 -3 10 -2 39.8581 29.9888 3 3 -10 3 2036.09 238.205 2 -3 10 -3 1785.72 156.011 3 3 10 3 1929.32 101.965 2 3 10 4 632.605 66.2307 2 3 -10 4 669.346 139.607 2 -3 10 -4 593.573 94.9929 3 3 10 5 361.761 57.9579 2 3 -10 5 335.109 107.093 2 -3 10 -5 382.018 83.2071 3 3 10 6 748.786 86.9165 2 3 -10 6 721.579 143.886 2 -3 10 -6 736.948 116.183 3 3 10 7 587.685 82.9283 2 3 -10 7 623.459 140.876 2 -3 10 -7 602.991 110.548 3 3 -10 8 350.988 100.948 2 3 10 8 415.243 71.4469 2 -3 10 -8 446.455 96.8697 3 3 -10 9 390.019 105.380 2 3 10 9 724.564 106.523 2 -3 10 -9 598.323 116.669 3 -3 10 -9 564.971 130.049 1 3 -10 10 410.129 110.283 2 -3 10 -10 386.520 107.774 1 3 10 10 467.833 90.4941 2 -3 10 -10 525.319 114.094 3 3 10 11 54.2196 40.9366 2 3 -10 11 38.1562 39.9981 2 -3 10 -11 56.0735 46.7267 1 -3 10 -11 80.1875 50.2679 3 3 10 12 37.3673 35.2895 2 3 -10 12-55.9511 62.9989 2 -3 10 -12 49.6309 40.6145 1 -3 10 -12-34.1790 41.1213 3 3 10 13 16.7647 29.2998 2 3 -10 13 36.3373 39.3878 2 -3 10 -13 21.9123 19.7826 3 -3 10 -13 68.7411 47.8155 1 3 -10 14 30.3815 29.1338 2 -3 10 -14-29.0775 18.2612 3 3 -10 15 203.869 100.274 2 -3 10 -15 180.192 74.2155 3 3 -10 16 3.98957 34.3879 2 -3 10 -16 12.3657 44.3810 3 -3 10 -17 96.8461 61.3625 3 -3 10 -18 33.9125 43.1280 3 -3 10 -19 13.7535 31.8559 3 -3 10 -20 0.24355 31.8209 3 -3 10 -21 17.4295 49.0245 3 3 -11 -21 1.13785 56.3125 2 3 -11 -20-8.46914 30.6801 2 3 -11 -19-65.5981 60.5583 2 3 -11 -18-65.5439 62.9206 2 3 -11 -17 25.2084 49.9885 2 3 -11 -16 46.5262 72.8270 2 3 -11 -15 287.940 115.631 2 3 -11 -14 628.757 166.847 2 -3 -11 14 371.608 82.7218 2 3 -11 -13 169.647 88.8260 2 -3 -11 13 87.9418 41.6674 2 -3 -11 12 1467.14 149.217 2 3 -11 -12 1970.55 262.670 2 -3 -11 11 405.419 77.7595 2 3 -11 -11 462.807 130.197 2 -3 -11 11 290.669 60.9485 2 -3 -11 10 132.900 42.6098 2 3 -11 -10 151.401 78.0451 2 -3 -11 10 113.820 32.9045 2 3 -11 -9-8.15325 34.8235 2 -3 -11 9 3.71709 14.9892 2 -3 -11 9 2.23057 22.8795 2 3 -11 -8 137.910 61.5823 2 -3 -11 8 159.547 31.8627 2 -3 -11 8 118.481 30.2961 2 -3 -11 7 124.867 24.5955 2 -3 -11 7 148.806 29.1545 2 3 -11 -7 324.724 103.686 2 -3 -11 6 634.871 52.8616 2 -3 -11 6 642.584 47.7032 2 3 -11 -6 1038.53 171.430 2 3 -11 -5-38.6140 44.6124 2 3 -11 -4 42.7263 36.6505 2 -3 11 4 70.4132 13.4468 3 -3 11 3 26.8382 14.7035 3 3 -11 -3-47.6337 46.2126 2 3 -11 -2-40.0902 44.3349 2 -3 11 2 2.66495 8.40718 3 3 -11 -1 19.4281 21.1779 2 -3 11 1 22.3858 10.5569 3 3 -11 0 81.1031 60.2144 2 -3 11 0 9.09905 11.3342 3 3 -11 1 316.968 112.256 2 -3 11 -1 17.4550 26.0990 3 3 -11 2 1839.81 228.225 2 -3 11 -2 1682.43 151.737 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578.901 102.342 2 4 -5 -14 249.029 80.4295 2 4 5 -14 628.984 104.706 1 -4 -5 13 2715.04 206.774 2 4 -5 -13 2154.51 98.0565 3 -4 5 13 2453.08 248.359 1 4 -5 -13 2626.78 276.450 2 -4 -5 12 1812.41 157.598 2 4 -5 -12 1330.52 67.4788 3 -4 5 12 1680.28 206.731 1 4 -5 -12 1672.20 214.397 2 -4 5 11 52.3305 52.2115 1 4 -5 -11-43.6527 50.6766 2 4 -5 -11-5.43569 3.52400 3 -4 -5 11-9.39152 22.9184 2 -4 5 10 677.849 127.129 2 -4 -5 10 474.709 70.8223 2 -4 5 10 530.757 117.267 1 4 -5 -10 590.991 124.569 2 4 -5 -9 8.15422 18.8863 2 -4 5 9 39.6529 44.3541 1 -4 5 9-14.7238 24.9947 2 -4 -5 9 0.69888 14.7391 2 -4 5 8 826.276 133.666 2 -4 -5 8 811.555 76.8779 2 4 -5 -8 644.194 119.116 2 -4 5 8 872.237 145.934 1 -4 5 7 213.671 71.3875 1 -4 5 7 258.559 72.5123 2 -4 -5 7 164.810 31.3066 2 4 -5 -7 133.929 18.3186 3 4 -5 -7 167.568 56.5599 2 -4 -5 6 119.886 24.6219 2 -4 5 6 154.280 58.9920 2 -4 5 6 116.296 52.2466 1 4 -5 -6 99.0053 18.9572 3 4 -5 -6 100.451 32.6105 2 -4 5 5 186.474 67.4490 2 -4 5 5 164.562 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5 1062.04 149.976 3 4 5 6 76.9508 33.4253 2 4 -5 6 17.3962 23.5158 2 4 -5 6 52.6439 38.1624 3 -4 5 -6 49.3476 41.3084 3 4 -5 7 117.454 62.4057 2 4 5 7 86.1489 36.7975 2 4 -5 7 83.5746 43.7948 3 -4 5 -7 104.126 47.9584 3 4 -5 8 452.730 112.539 2 4 5 8 429.388 83.8014 2 4 -5 8 407.476 96.5907 3 -4 5 -8 502.580 95.0354 3 4 -5 9-13.4032 53.7502 2 4 5 9 126.694 49.9899 2 4 -5 9 133.659 58.4569 3 -4 5 -9 127.151 48.0377 3 4 5 10 46.5402 18.7436 2 -4 5 -10 13.7174 28.9464 3 4 5 11 64.0391 33.8522 2 -4 5 -11 48.1461 27.1686 3 4 5 12 29.6999 19.3143 2 -4 5 -12 49.1846 40.8934 3 4 5 13 131.702 60.1856 2 -4 5 -13 230.136 78.3266 3 -4 5 -14 238.757 80.8241 3 -4 5 -15 115.829 60.0073 3 -4 5 -16 158.544 76.6421 3 -4 5 -17 908.129 174.638 3 -4 5 -18 4.82418 34.1446 3 -4 5 -19 24.8653 51.4755 3 -4 5 -20 72.5041 58.3711 3 -4 5 -21 29.7636 31.6620 3 -4 5 -22-30.0689 41.8371 3 4 6 -26 69.0583 71.7493 3 4 6 -25 141.470 87.9527 3 4 -6 -24 84.7526 94.7872 2 4 6 -24-14.2002 26.7954 3 4 -6 -23 71.5539 63.6884 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60.3638 2 -4 6 -14 509.468 119.796 3 -4 6 -15 23.6556 34.5517 3 -4 6 -16 171.634 77.8529 3 -4 6 -17 189.841 89.4669 3 -4 6 -18 96.4408 54.6484 3 -4 6 -19-59.3059 49.3561 3 -4 6 -20 11.8114 33.0900 3 -4 6 -21 51.5344 49.8157 3 4 7 -25 74.4225 54.1618 3 4 -7 -24 58.7998 96.8201 2 4 -7 -23 48.8659 79.8159 2 4 -7 -22 88.1277 87.9158 2 4 -7 -21 39.9640 52.3095 2 4 -7 -20-38.8802 47.1779 2 4 7 -19 72.6479 38.5171 1 4 -7 -19 176.097 85.1649 2 4 7 -18 90.6038 43.7967 1 4 -7 -18 174.234 96.7005 2 -4 -7 17 159.347 52.9220 2 4 7 -17 418.279 87.0939 1 4 -7 -17 382.608 122.069 2 -4 -7 16 32.3249 27.4070 2 4 -7 -16 67.4021 56.1550 2 -4 -7 15 4.14738 13.8339 2 4 -7 -15-60.7201 64.4034 2 -4 -7 14 251.620 60.5495 2 4 -7 -14 179.167 70.9922 2 -4 -7 13 225.570 56.4701 2 4 -7 -13 80.7955 51.3599 2 -4 -7 12 57.4770 29.5461 2 4 -7 -12 6.54489 28.9129 2 -4 -7 11 2119.09 145.494 2 4 -7 -11 2318.97 260.457 2 -4 -7 10 1209.21 98.6217 2 4 -7 -10 1236.06 188.625 2 -4 -7 9 629.544 60.6152 2 4 -7 -9 711.923 139.600 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58.7180 29.6320 2 -4 7 -7 91.9409 61.4899 3 4 -7 8 22.2261 39.3207 2 4 7 8 5.04868 14.1817 2 -4 7 -8-15.2594 19.1185 3 4 -7 9-1.78405 35.2531 2 4 7 9 30.0168 19.7803 2 -4 7 -9 47.7173 33.6728 3 4 -7 10-9.26241 37.1239 2 4 7 10 73.6543 33.6341 2 -4 7 -10 42.1520 33.8975 3 4 -7 11 576.537 140.447 2 4 7 11 404.727 87.6361 2 -4 7 -11 453.031 105.611 3 4 -7 12-18.4338 48.8824 2 4 7 12 15.6333 20.6364 2 -4 7 -12-14.2927 30.8569 3 4 -7 13 659.565 158.026 2 -4 7 -13 979.448 162.864 3 4 7 13 606.194 118.445 2 4 -7 14 60.5243 48.9048 2 -4 7 -14 8.94847 28.2662 3 -4 7 -15 117.182 67.0928 3 -4 7 -16-8.49896 41.5288 3 -4 7 -17 228.208 84.8361 3 -4 7 -18 50.9048 50.6688 3 -4 7 -19 13.7409 27.0660 3 -4 7 -20 37.1770 44.0371 3 -4 7 -21 58.8772 73.2585 3 4 -8 -23 13.8947 32.4452 2 4 -8 -22-22.0876 41.0455 2 4 -8 -21 49.0341 80.9487 2 4 -8 -20 109.730 87.6692 2 4 -8 -19 36.9853 76.2221 2 4 8 -18 161.275 54.5384 1 4 -8 -18 82.6906 73.1196 2 4 -8 -17 59.2444 56.1334 2 -4 -8 16 355.370 85.4294 2 4 -8 -16 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48.7879 1 7 4 -11 252.981 109.623 1 7 -4 -11 224.007 90.5275 2 7 -4 -10 0.67025 33.3226 2 7 4 -10 45.8443 51.7529 1 7 -4 -9-16.7239 27.8777 2 7 4 -9 46.5153 47.5023 1 7 -4 -8-36.8256 25.0587 2 7 4 -8 13.6108 50.5129 1 7 -4 -7 69.0577 63.6344 2 7 4 -7 97.8795 71.5159 1 7 4 -6 634.021 146.264 1 7 -4 -6 442.616 114.694 2 7 4 -5 220.656 89.8647 1 7 -4 -5 23.7910 41.3747 2 7 4 -4 107.045 72.9334 1 7 -4 -4-75.2572 47.4589 2 7 4 -3 110.646 71.7824 1 7 -4 -3-36.9967 45.2469 2 7 4 -2 254.746 88.7785 1 7 -4 -2 73.7004 39.7538 2 7 -4 -1 121.785 55.6078 2 7 -4 0-2.19834 38.2527 2 7 -4 1 17.9128 35.6617 2 7 -4 2-39.0300 29.9942 2 7 -4 2-36.7283 57.1871 1 7 -4 3 101.279 56.0657 2 7 -4 3-5.44828 61.5474 1 7 -4 4 132.261 60.8610 2 7 -4 4 151.880 86.2232 1 7 -4 5 4.48406 23.9586 2 7 -4 5 11.2247 46.8260 1 7 -4 6 26.9472 42.6148 2 7 -4 6-27.2372 59.8806 1 7 -4 7 11.6964 42.7784 2 7 -4 7-39.4711 72.3662 1 7 -4 8 5.48200 26.0605 2 7 -4 8-10.7043 69.8049 1 7 -4 9-15.4761 31.9701 2 7 -4 9-104.941 81.3738 1 7 -4 10-40.4409 44.2476 2 7 -4 11 47.1483 57.1731 2 7 -4 12 0.12119 40.9971 2 7 -4 13 2.54369 25.9390 2 7 4 14 177.182 108.966 1 7 -4 14-43.5553 50.5941 2 7 -5 -19 40.6584 69.4101 2 7 -5 -18 26.0062 63.3626 2 7 5 -17 31.2432 56.3514 1 7 -5 -17 0.26898 47.9015 2 7 5 -16-4.63684 44.1556 1 7 -5 -16-45.8210 48.7951 2 7 -5 -15-12.6531 31.4340 2 7 5 -15 24.0207 57.1211 1 7 -5 -14-60.9672 52.7134 2 7 5 -14-24.9723 30.9239 1 7 5 -13 62.3232 63.1943 1 7 -5 -13-11.7575 29.3197 2 7 -5 -12 2.74027 23.2277 2 7 5 -12 125.486 75.4805 1 7 -5 -11 1.57370 31.2992 2 7 5 -11 50.4370 56.1069 1 7 5 -10 30.9739 60.0667 1 7 -5 -10 48.7962 46.1010 2 7 -5 -9 0.09635 19.4571 2 7 5 -9 76.1990 55.4219 1 7 -5 -8-12.5739 20.6901 2 7 5 -8 115.208 69.5274 1 7 -5 -7 123.242 64.5125 2 7 5 -7 111.269 73.4090 1 7 5 -6 130.984 81.4575 1 7 -5 -6-14.6329 35.9465 2 7 -5 -5 33.0516 27.7697 2 7 -5 -4 16.2912 20.6170 2 7 -5 -3 66.4117 37.9705 2 7 -5 -2-21.1094 37.2569 2 7 -5 -1 57.0624 38.4622 2 7 -5 0 17.9824 44.7343 2 7 -5 1 165.738 65.4336 2 7 -5 2 0.63374 33.3071 2 7 -5 3 77.6945 47.6421 2 7 -5 4-55.6418 48.8675 2 7 -5 5-50.3146 45.4295 2 7 -5 6 16.9741 24.8646 2 7 -5 7 44.0379 56.7676 2 7 -5 8 32.7429 39.8470 2 7 -5 9 34.0322 61.6463 2 7 -5 10 2.08238 34.8591 2 7 -5 11 9.48049 29.9803 2 7 -5 12 24.8204 59.0626 2 7 -5 13 14.9427 57.8220 2 7 -6 -18 15.2927 63.7979 2 7 6 -17-7.88159 38.4336 1 7 -6 -17-48.0825 51.2047 2 7 -6 -16-9.50233 29.4345 2 7 6 -16 56.3499 65.1684 1 7 -6 -15-81.2261 62.3924 2 7 6 -15 7.58607 58.6165 1 7 6 -14-46.0992 57.3570 1 7 -6 -14-52.7413 50.2851 2 7 -6 -13-27.8816 39.9858 2 7 6 -13 89.0965 66.2441 1 7 6 -12 108.645 77.6139 1 7 -6 -12 99.8073 68.1126 2 7 -6 -11 8.89225 44.3245 2 7 6 -11 74.6872 56.1877 1 7 -6 -10 109.304 72.5622 2 7 6 -10 183.068 90.7837 1 7 -6 -9 69.1272 58.3863 2 7 6 -9 123.628 64.3755 1 7 6 -8 110.417 69.0177 1 7 -6 -8 47.6171 43.7561 2 7 -6 -7 205.073 92.4759 2 7 -6 -6 16.2802 47.4207 2 7 -6 -5-37.3783 56.7408 2 7 -6 -4-195.039 79.3751 2 7 -6 -3 47.7836 55.7367 2 7 -6 -2 139.527 73.3515 2 7 -6 -1 151.615 78.7923 2 7 -6 0 307.596 102.117 2 7 -6 1 28.0616 46.2153 2 7 -6 2 15.4134 29.2721 2 7 -6 3 42.8920 41.5448 2 7 -6 4 21.2818 34.1947 2 7 -6 5-61.2384 51.0298 2 7 -6 6 61.3539 60.4082 2 7 -6 7-39.4833 43.8933 2 7 -6 8 6.59191 34.0425 2 7 -6 9-0.11716 25.7946 2 7 -6 10 0.12170 42.8054 2 7 -6 11 40.5828 47.1158 2 7 -6 12-52.5476 52.5851 2 7 -7 -17 2.50518 37.6406 2 7 7 -16-77.3745 61.6242 1 7 -7 -16-20.1867 40.3638 2 7 7 -15 6.29423 45.6113 1 7 -7 -15 0.13780 37.3549 2 7 -7 -14 11.8514 31.2486 2 7 7 -14 4.84261 19.9611 1 7 -7 -13 68.4593 73.0551 2 7 7 -13 32.9748 37.5249 1 7 7 -12 161.222 83.2596 1 7 -7 -12 38.7014 67.0679 2 7 -7 -11 5.18083 36.0296 2 7 7 -11 98.4567 72.0392 1 7 -7 -10 54.1679 44.1273 2 7 -7 -9 134.878 89.4547 2 7 -7 -8 60.4606 79.7737 2 7 -7 -7 225.980 104.442 2 7 -7 -6 112.813 82.3615 2 7 -7 -5 113.955 78.4633 2 7 -7 -4 0.51389 37.4402 2 7 -7 -3-62.8474 50.5206 2 7 -7 -2-65.4643 51.1713 2 7 -7 -1-79.0641 55.5277 2 7 -7 0 16.7462 47.1903 2 7 -7 1 121.606 71.7849 2 7 -7 2 169.889 89.0292 2 7 -7 3 61.9322 59.9518 2 7 -7 4 18.3556 36.1932 2 7 -7 5 0.11306 30.3319 2 7 -7 6-40.2378 45.2843 2 7 -7 7 46.9334 42.2786 2 7 -7 8 0.72024 57.1720 2 7 -7 9-2.32460 25.6662 2 7 -7 10 36.7014 54.4048 2 7 -7 11 50.7963 79.0301 2 7 8 -16-59.2924 53.2636 1 7 8 -15 58.3228 59.7778 1 7 -8 -15-122.637 80.0812 2 7 -8 -14-0.13957 51.4514 2 7 8 -14 39.2281 51.3237 1 7 -8 -13 0.13481 35.1768 2 7 8 -13 115.211 69.9739 1 7 -8 -12-51.8746 50.8086 2 7 8 -12 65.4302 71.8620 1 7 -8 -11-60.6305 53.6457 2 7 -8 -10 76.3139 69.9216 2 7 -8 -9 71.7971 83.2377 2 7 -8 -8 35.0127 58.1261 2 7 -8 -7 151.405 94.6399 2 7 -8 -6 344.065 130.247 2 7 -8 -5 101.468 83.6678 2 7 -8 -4 5.33896 48.8586 2 7 -8 -3 62.2259 57.1147 2 7 -8 -2-34.4468 41.5978 2 7 -8 -1 8.38402 30.6650 2 7 -8 0 23.1898 35.7472 2 7 -8 1 2.67866 25.2283 2 7 -8 2 0.11184 36.4985 2 7 -8 3 46.0146 66.5153 2 7 -8 4 456.230 137.532 2 7 -8 5 150.665 93.1149 2 7 -8 6-74.3802 58.6999 2 7 -8 7-70.2101 57.2762 2 7 -8 8 5.66676 50.9775 2 7 -8 9 0.51506 42.1628 2 7 9 -15 31.8958 64.1798 1 7 9 -14 244.564 114.158 1 7 -9 -13 0.14398 33.1166 2 7 -9 -12-6.81851 30.3657 2 7 -9 -11 72.7387 78.1346 2 7 -9 -10 76.4430 83.2623 2 7 -9 -9 30.0287 54.4712 2 7 -9 -8 35.7741 69.0653 2 7 -9 -7 96.9487 85.4731 2 7 -9 -6-50.4341 50.2305 2 7 -9 -5 138.965 88.2755 2 7 -9 -4 69.1930 77.3288 2 7 -9 -3-43.4500 47.6064 2 7 -9 -2 19.6651 26.8842 2 7 -9 -1-135.608 75.6421 2 7 -9 0 1.08230 38.7347 2 7 -9 1 46.7262 69.0715 2 7 -9 2 57.7878 72.5853 2 7 -9 3 162.864 95.2318 2 7 -9 4 120.724 92.6663 2 7 -9 5 77.8975 61.8309 2 7 -9 6 18.9642 47.9427 2 7 -9 7-51.9998 54.0694 2 7 10 -15 30.9873 48.0661 1 7 -10 -10 50.9336 82.1952 2 7 -10 -9 56.0701 84.5594 2 7 -10 -8 99.3265 82.4610 2 7 -10 -7 65.1322 82.7889 2 7 -10 -6 3.42513 65.5361 2 7 -10 -5 123.815 81.4109 2 7 -10 -4 45.5698 77.5498 2 7 -10 -3 24.8558 48.7238 2 7 -10 -2 2.32722 37.6899 2 7 -10 -1-52.9604 52.7048 2 7 -10 0 17.0358 44.3327 2 7 -10 1-12.5786 27.4413 2 7 -10 2 0.12848 34.2178 2 7 -10 3 44.3898 52.2515 2 7 -10 4 18.0026 50.9595 2 7 -11 -4 31.2000 55.6263 2 7 -11 -3 82.4459 77.4451 2 7 -11 -2 0.13870 37.6491 2 7 -11 -1-119.736 78.2170 2 8 0 -11-59.9632 64.0552 1 8 0 -10-235.973 119.229 1 8 0 -9-58.3758 82.6863 1 8 0 -8 159.610 107.451 1 8 0 -7 19.8965 45.7364 1 8 0 -6 32.8188 56.3601 1 8 0 -5 47.4609 65.0132 1 8 0 -4 144.725 81.7657 1 8 0 -3 85.9005 56.7691 1 8 0 -2-67.9300 71.7193 1 8 0 -1-121.010 80.4949 1 8 0 -1 17.4656 27.3170 2 8 0 0 38.8416 52.4872 1 8 0 0 6.39463 16.9698 2 8 0 1 18.3172 70.7958 1 8 0 1 18.8946 28.3551 2 8 0 2 3.28989 20.6107 2 8 0 2 35.3965 51.9549 1 8 0 3 36.0268 37.6615 1 8 0 4 6.16493 41.6036 1 8 0 5 6.30858 50.4643 1 8 1 -13-176.966 106.257 1 8 1 -12-29.0505 86.2297 1 8 1 -11-25.1737 53.4496 1 8 1 -10 22.3000 62.0428 1 8 -1 -10-129.591 66.4303 2 8 1 -9 2.03573 27.9154 1 8 -1 -9-85.2991 53.3363 2 8 -1 -8-19.3832 28.9930 2 8 1 -8-20.8528 57.2175 1 8 -1 -8-64.0757 79.1409 1 8 -1 -7 101.891 58.9964 2 8 1 -7 179.454 102.195 1 8 -1 -7 11.2766 44.5943 1 8 -1 -6 0.08159 45.9466 2 8 1 -6 41.5685 43.7776 1 8 -1 -6-42.0413 56.6278 1 8 -1 -5 39.5762 37.9450 1 8 -1 -5 65.0226 52.2223 2 8 -1 -4-16.6300 26.1205 1 8 1 -4-16.8699 40.5236 1 8 -1 -4 25.2023 42.0634 2 8 -1 -3 66.8064 62.2348 1 8 -1 -3 20.7039 21.2189 2 8 -1 -2 3.51133 36.0841 1 8 -1 -2-30.1568 39.0195 2 8 -1 -1 26.1594 40.3194 1 8 -1 -1 14.0956 24.9004 2 8 1 -1 51.4874 69.8229 1 8 -1 0 197.158 108.601 1 8 -1 0 190.254 77.4935 2 8 1 0 166.748 98.5846 1 8 -1 1 46.2264 75.3420 1 8 -1 1-13.9338 34.8324 2 8 1 1 17.0661 55.8338 1 8 1 2 15.1789 90.6213 1 8 -1 2 11.3314 42.0060 1 8 -1 2 98.9608 57.2056 2 8 1 3 156.792 97.4444 1 8 -1 3 41.2621 69.0371 1 8 -1 3 73.8645 55.5313 2 8 1 4 59.6634 70.6600 1 8 -1 4-30.1234 54.2072 1 8 -1 4 22.0782 36.5756 2 8 1 5 116.873 89.5398 1 8 -1 5 66.3490 78.8631 1 8 -1 5 98.6425 63.7633 2 8 -1 6 31.0326 47.8269 2 8 -1 7 106.259 64.4338 2 8 -1 8 7.47569 25.8101 2 8 -1 9 15.5542 32.4086 2 8 -1 10-26.6292 40.2312 2 8 -2 -15-10.5052 32.9032 2 8 -2 -14-52.3001 49.4297 2 8 2 -14-125.515 92.3837 1 8 -2 -13-0.11485 48.1230 2 8 2 -13-42.2407 74.9141 1 8 2 -12-65.2600 55.2769 1 8 -2 -12-99.6590 62.8848 2 8 2 -11 228.161 126.794 1 8 -2 -11 81.9478 66.5062 2 8 2 -10 73.1417 71.3934 1 8 -2 -10 5.64444 46.8414 2 8 -2 -9-6.82388 23.8763 2 8 2 -9 33.3345 34.1683 1 8 -2 -8 2.68720 21.4163 2 8 2 -8 81.4257 72.6197 1 8 -2 -7 23.6689 50.8850 2 8 2 -7-41.5164 47.4047 1 8 -2 -6 66.8544 47.5011 2 8 2 -6 146.216 90.7863 1 8 -2 -5 46.9596 39.6506 2 8 -2 -5 21.7601 63.5106 1 8 2 -5-20.8880 71.0608 1 8 -2 -4-87.1675 76.1867 1 8 -2 -4 60.9324 47.9757 2 8 2 -4 40.8850 44.7040 1 8 2 -3 96.7227 69.5402 1 8 -2 -3-55.5195 41.7010 2 8 -2 -3-53.1259 70.2958 1 8 2 -2 97.6929 71.0479 1 8 -2 -2-53.3062 40.6048 2 8 -2 -2 1.23307 50.2085 1 8 -2 -1-10.7299 64.1582 1 8 2 -1 128.373 75.6112 1 8 -2 -1 20.6475 21.3548 2 8 -2 0-88.3663 87.8227 1 8 2 0-12.1397 40.9634 1 8 -2 0-50.8431 39.7958 2 8 -2 1 36.5099 35.5512 1 8 2 1 50.0743 77.6297 1 8 -2 1 2.70835 28.2655 2 8 2 2 35.8337 43.6860 1 8 -2 2 39.7887 48.0611 2 8 -2 3 6.74379 66.9197 1 8 2 3-9.41459 48.1985 1 8 -2 3 44.1635 48.6443 2 8 -2 4-15.4051 37.4090 1 8 -2 4 14.9628 39.3938 2 8 2 4 45.7583 64.4531 1 8 -2 5 6.82119 35.2388 1 8 -2 5 57.8331 61.2866 2 8 -2 6-27.7780 34.4966 2 8 -2 7-0.09876 21.8042 2 8 -2 8-42.0364 43.8959 2 8 -2 9 62.8122 62.5435 2 8 -2 10 0.11171 32.5175 2 8 -2 11 32.2585 67.6251 2 8 -2 12 1.98460 47.6574 2 8 -3 -17 1.92632 72.6400 2 8 -3 -16 0.39550 41.7080 2 8 3 -16-170.470 109.255 1 8 -3 -15 0.12753 52.9134 2 8 3 -15-151.949 102.048 1 8 3 -14-35.0212 66.5765 1 8 -3 -14 0.36855 35.7696 2 8 3 -13 26.8276 34.7878 1 8 -3 -13-44.6996 47.7258 2 8 3 -12 16.4898 45.4693 1 8 -3 -12-0.11346 55.1820 2 8 -3 -11 0.10848 42.4561 2 8 3 -11-8.74106 23.8185 1 8 -3 -10 0.20789 25.7566 2 8 3 -10 70.6198 83.3004 1 8 -3 -9-49.8469 43.4670 2 8 3 -9 45.3519 61.4171 1 8 -3 -8 8.16374 32.8121 2 8 3 -8-14.6325 45.4967 1 8 3 -7-28.8249 27.3677 1 8 -3 -7 1.01120 28.9071 2 8 -3 -6 14.8869 28.0141 2 8 3 -6-28.9467 65.6928 1 8 3 -5 16.0472 48.3829 1 8 -3 -5-1.13112 17.6011 2 8 3 -4 41.2115 56.2724 1 8 -3 -4-74.8843 48.5148 2 8 3 -3 151.341 97.1863 1 8 -3 -3-42.8230 38.6496 2 8 3 -2 58.1103 52.6394 1 8 -3 -2 0.08553 24.1841 2 8 -3 -1-44.0343 39.1394 2 8 -3 -1-160.034 98.9763 1 8 3 0 59.7342 48.6215 1 8 -3 0 58.3807 39.2971 2 8 -3 0 24.3955 71.6310 1 8 3 1 12.4849 31.4216 1 8 -3 1 21.8277 31.0521 2 8 -3 2 41.1024 51.2885 2 8 -3 2-38.8556 80.3793 1 8 3 3 47.7189 85.0151 1 8 -3 3 19.2994 30.7620 2 8 -3 3-23.5851 96.4909 1 8 -3 4 8.35661 44.4317 2 8 -3 4-79.4781 91.6841 1 8 -3 5 54.3167 55.3832 2 8 -3 6 14.4148 48.0675 2 8 -3 7 37.5662 44.6623 2 8 -3 8 2.90101 39.7217 2 8 -3 9 7.82678 31.6440 2 8 -3 10 1.04706 30.7357 2 8 -3 11-56.9727 53.4976 2 8 -3 12 0.25659 53.9614 2 8 -4 -17 5.05687 54.7413 2 8 4 -16 25.4761 67.1817 1 8 -4 -16-48.0583 52.8244 2 8 4 -15 40.0093 75.4741 1 8 -4 -15 0.13132 45.5228 2 8 4 -14 0.18010 54.1491 1 8 -4 -14 0.25478 34.1912 2 8 4 -13 44.7630 81.9950 1 8 -4 -13 0.24466 36.4018 2 8 -4 -12-14.3443 31.2285 2 8 4 -12 40.5961 77.0101 1 8 -4 -11 20.3177 34.1945 2 8 4 -11 72.5857 58.5183 1 8 -4 -10 12.1703 28.6414 2 8 4 -10 34.9947 30.3232 1 8 4 -9-7.30929 28.3551 1 8 -4 -9 32.3698 50.9980 2 8 -4 -8 97.0777 74.7791 2 8 4 -8 88.6161 81.7487 1 8 -4 -7 43.7191 61.9377 2 8 4 -7-8.87414 40.7947 1 8 -4 -6-9.79254 24.3879 2 8 4 -6-23.0132 45.0718 1 8 4 -5 141.152 80.3438 1 8 -4 -5 2.78718 22.8790 2 8 4 -4-10.4241 32.3285 1 8 -4 -4-59.1847 45.4437 2 8 4 -3 141.796 85.4802 1 8 -4 -3-18.2472 40.1470 2 8 4 -2 51.9484 46.7334 1 8 -4 -2-67.8815 48.1095 2 8 4 -1 18.1293 20.3638 1 8 -4 -1-29.8443 35.0315 2 8 -4 0 2.76665 20.8268 2 8 4 0 48.5725 71.8290 1 8 4 1 192.260 109.752 1 8 -4 1 112.793 64.1783 2 8 4 2 151.481 89.4359 1 8 -4 2 35.9701 58.4604 2 8 -4 3 55.0009 59.1925 2 8 -4 4 98.4487 69.2902 2 8 -4 5 94.5222 67.8420 2 8 -4 6 26.8088 61.3207 2 8 -4 7 19.1840 52.5967 2 8 -4 8-37.3345 42.6449 2 8 -4 9-38.0668 43.7471 2 8 -4 10 28.3939 42.0981 2 8 5 -16-70.3481 78.7969 1 8 -5 -16-0.14064 46.3092 2 8 5 -15 16.5367 79.7684 1 8 -5 -15 0.27270 33.0236 2 8 -5 -14 0.92889 50.6329 2 8 5 -14 37.5630 78.4119 1 8 -5 -13 12.7953 36.4820 2 8 5 -13 75.0653 66.7577 1 8 -5 -12-88.6811 61.9825 2 8 5 -12 37.6282 54.6265 1 8 5 -11-38.4556 48.9022 1 8 -5 -11-19.0973 33.5133 2 8 -5 -10 0.11289 41.4246 2 8 5 -10-62.9803 57.9584 1 8 -5 -9 0.10919 49.6985 2 8 5 -9-22.6941 48.5048 1 8 -5 -8 42.3498 52.5180 2 8 5 -8 104.796 83.7599 1 8 5 -7 70.6791 58.3996 1 8 -5 -7 12.1715 55.4799 2 8 -5 -6 9.79531 46.8186 2 8 5 -6 22.5334 36.9105 1 8 5 -5 24.9526 42.8957 1 8 -5 -5 14.3321 19.4928 2 8 5 -4 100.139 70.4665 1 8 -5 -4-91.6880 56.9036 2 8 5 -3 73.2556 73.3517 1 8 -5 -3 0.09825 40.6947 2 8 5 -2 152.928 93.6890 1 8 -5 -2-30.8750 36.5622 2 8 5 -1 61.4163 82.1215 1 8 -5 -1 0.09838 40.1453 2 8 5 0 72.3293 80.5987 1 8 -5 0-23.2077 33.5921 2 8 -5 1 14.5680 31.2898 2 8 -5 2 47.5370 61.5265 2 8 -5 3 151.606 83.9340 2 8 -5 4 22.4079 61.0783 2 8 -5 5 144.556 87.8275 2 8 -5 6 55.7918 71.0037 2 8 -5 7 0.11511 23.0812 2 8 -5 8 72.8519 73.0730 2 8 -5 9 1.71243 52.0861 2 8 6 -15 2.11810 32.3048 1 8 -6 -14-0.13676 47.1460 2 8 6 -14 99.7375 94.4024 1 8 -6 -13 7.10450 53.4150 2 8 6 -13-72.9124 64.3965 1 8 6 -12-10.9267 28.7862 1 8 -6 -12-39.9357 45.5804 2 8 -6 -11-32.9651 40.6278 2 8 6 -11-6.24926 37.5968 1 8 -6 -10 7.34603 48.7593 2 8 6 -10 60.2373 60.0780 1 8 6 -9 88.9601 85.8666 1 8 -6 -9 0.11503 25.8421 2 8 -6 -8 8.42126 40.5037 2 8 6 -8 120.691 88.8444 1 8 -6 -7 0.10938 50.9628 2 8 6 -7 47.7781 55.5257 1 8 6 -6 93.6598 73.1449 1 8 -6 -6 50.0544 67.5319 2 8 6 -5 71.3055 65.1018 1 8 -6 -5 24.5089 56.7618 2 8 6 -4 163.835 87.8175 1 8 -6 -4 23.2101 40.9158 2 8 6 -3 106.731 106.120 1 8 -6 -3 2.21374 52.7297 2 8 -6 -2 0.21034 40.0557 2 8 -6 -1-58.1342 48.6752 2 8 -6 0-58.3124 48.9759 2 8 -6 1 32.3545 46.8672 2 8 -6 2 19.0714 33.2928 2 8 -6 3 59.7972 55.0390 2 8 -6 4 48.0228 60.7817 2 8 -6 5 50.6846 75.6866 2 8 -6 6 48.7267 65.5277 2 8 -6 7 11.1719 52.0749 2 8 7 -14-28.3110 47.0980 1 8 7 -13-52.6424 55.1362 1 8 7 -12 24.3746 43.7345 1 8 7 -11-6.43083 24.6319 1 8 -7 -11-50.2540 51.9137 2 8 -7 -10-63.0783 54.7524 2 8 7 -10 107.087 91.3127 1 8 7 -9 114.398 103.766 1 8 -7 -9 25.7184 65.1250 2 8 -7 -8 30.5361 76.5898 2 8 7 -8 140.155 96.0559 1 8 -7 -7 104.406 84.2180 2 8 7 -7 266.271 123.448 1 8 -7 -6 20.8897 59.6400 2 8 -7 -5 0.11435 20.9067 2 8 -7 -4-0.11381 21.3139 2 8 -7 -3-19.4768 33.7594 2 8 -7 -2-45.5168 45.2047 2 8 -7 -1-30.9683 38.8484 2 8 -7 0-22.5745 34.8755 2 8 -7 1 27.6621 48.1033 2 8 -7 2 31.7130 63.4633 2 8 -7 3 60.8832 65.3624 2 8 -7 4 0.11688 46.0049 2 8 -7 5 0.59355 40.8754 2 8 -8 -7 0.12430 53.7011 2 8 -8 -6 46.4597 65.4155 2 8 -8 -5 0.61335 24.9070 2 8 -8 -4-54.3207 51.9262 2 8 -8 -3 0.12171 43.1178 2 8 -8 -2 0.12132 45.3198 2 8 -8 -1 0.12153 41.2715 2 8 -8 0-90.1128 63.8260 2 8 -8 1 0.12274 28.6679 2 0 0 0 0.00 0.00 0 TITL bmk1637b in P2(1)/c REM P2(1)/c (#14 in standard setting) CELL 0.71073 6.663062 15.229710 22.431273 90.0000 96.3901 90.0000 ZERR 4.00 0.000595 0.001710 0.002582 0.0000 0.0092 0.0000 LATT 1 SYMM -x, y+1/2,-z+1/2 SFAC C H N O UNIT 88.00 48.00 8.00 8.00 TREF HKLF 4 END ; _shelx_hkl_checksum 51258 _shelx_res_file ; TITL bmk1637b in P2(1)/c shelx.res created by SHELXL-2018/1 at 16:22:09 on 22-Feb-2019 CELL 0.71073 6.6631 15.2297 22.4313 90.000 96.390 90.000 ZERR 4.00 0.0006 0.0017 0.0026 0.000 0.009 0.000 LATT 1 SYMM - X, 1/2 + Y, 1/2 - Z SFAC C H N O CL F S UNIT 104 68 12 4 4 4 4 MERG 2 mpla c1 c2 c3 c4 c5 c6 c7 c8 o1 mpla c9 c10 c11 n1 s1 mpla c12 c13 c14 n3 n4 mpla c21 c22 c23 c24 c25 c26 Cl1 mpla c15 c16 c17 c18 c19 c20 F1 mpla c12 c13 c14 n3 n4 EQIV $1 -x-1, -y+1, -z HTAB C19 F1_$1 shel 99999 .80 FMAP 2 PLAN 5 SIZE 0.113 0.189 0.460 ACTA BOND $H L.S. 4 TEMP 23.00 WGHT 0.054200 0.682500 FVAR 2.10008 MOLE 1 C1 1 -0.041977 0.915254 0.165572 11.00000 0.06346 0.06300 = 0.05591 -0.00232 -0.00488 0.00414 C2 1 -0.226384 0.883990 0.172088 11.00000 0.06649 0.07074 = 0.06030 -0.00443 -0.00328 0.00492 AFIX 43 H2 2 -0.315276 0.858931 0.141930 11.00000 -1.20000 AFIX 0 C3 1 -0.263598 0.895646 0.233298 11.00000 0.07125 0.06232 = 0.06176 0.00237 -0.00271 0.00899 C4 1 -0.087341 0.935339 0.260725 11.00000 0.07546 0.06472 = 0.05858 0.00376 -0.00072 0.01089 C5 1 -0.419304 0.878535 0.267961 11.00000 0.08525 0.08387 = 0.07203 0.00931 0.00773 0.00036 AFIX 43 H5 2 -0.538290 0.852152 0.251208 11.00000 -1.20000 AFIX 0 C6 1 -0.393733 0.901355 0.327291 11.00000 0.11474 0.09321 = 0.07085 0.01604 0.01922 0.00922 AFIX 43 H6 2 -0.497815 0.891053 0.350794 11.00000 -1.20000 AFIX 0 C7 1 -0.217166 0.939281 0.353036 11.00000 0.13247 0.09327 = 0.05826 0.00163 0.00929 0.00571 AFIX 43 H7 2 -0.204363 0.952927 0.393693 11.00000 -1.20000 AFIX 0 C8 1 -0.058676 0.957614 0.320216 11.00000 0.10997 0.09300 = 0.06305 -0.00681 -0.00594 -0.00311 AFIX 43 H8 2 0.060249 0.983506 0.337468 11.00000 -1.20000 AFIX 0 C9 1 0.072465 0.918663 0.114728 11.00000 0.05973 0.05913 = 0.05718 0.00156 0.00076 0.00068 C10 1 0.268548 0.940846 0.114686 11.00000 0.06811 0.07719 = 0.06743 -0.00811 0.00424 -0.01155 AFIX 43 H10 2 0.351786 0.959633 0.148300 11.00000 -1.20000 AFIX 0 C11 1 0.100131 0.895929 0.019893 11.00000 0.06959 0.05763 = 0.06306 0.00366 0.00388 -0.00654 C12 1 -0.151036 0.829271 -0.058000 11.00000 0.05699 0.07681 = 0.06321 -0.00063 0.00092 -0.00637 AFIX 13 H12 2 -0.261981 0.869744 -0.052668 11.00000 -1.20000 AFIX 0 C13 1 -0.130413 0.817776 -0.124710 11.00000 0.07153 0.10896 = 0.06095 0.00936 0.00029 -0.02072 AFIX 23 H13A 2 -0.154473 0.757287 -0.137032 11.00000 -1.20000 H13B 2 -0.224552 0.855387 -0.148931 11.00000 -1.20000 AFIX 0 C14 1 0.083013 0.843929 -0.130247 11.00000 0.05908 0.05626 = 0.06343 0.00589 -0.00016 -0.00513 C15 1 -0.180516 0.743795 -0.025717 11.00000 0.05706 0.07214 = 0.05131 -0.00775 0.00522 -0.00297 C16 1 -0.022123 0.694124 0.000017 11.00000 0.06661 0.08110 = 0.09619 0.00463 0.00117 -0.00707 AFIX 43 H16 2 0.109071 0.713957 -0.001787 11.00000 -1.20000 AFIX 0 C17 1 -0.051599 0.616089 0.028321 11.00000 0.09008 0.07764 = 0.09750 0.00175 -0.01043 -0.00011 AFIX 43 H17 2 0.057272 0.583478 0.045913 11.00000 -1.20000 AFIX 0 C18 1 -0.242920 0.587972 0.029924 11.00000 0.12191 0.07261 = 0.05664 0.00097 0.00356 -0.01608 C19 1 -0.406064 0.633525 0.004757 11.00000 0.08227 0.09762 = 0.07511 -0.00863 0.02267 -0.02738 AFIX 43 H19 2 -0.536128 0.611895 0.005850 11.00000 -1.20000 AFIX 0 C20 1 -0.373543 0.713241 -0.022647 11.00000 0.06097 0.08595 = 0.06537 -0.00459 0.00905 -0.00522 AFIX 43 H20 2 -0.483302 0.746331 -0.039096 11.00000 -1.20000 AFIX 0 C21 1 0.177550 0.841647 -0.185886 11.00000 0.06818 0.05207 = 0.05841 0.00476 0.00288 -0.00098 C22 1 0.078510 0.801996 -0.237032 11.00000 0.08801 0.07317 = 0.07071 -0.00016 0.00415 -0.01617 AFIX 43 H22 2 -0.047482 0.776451 -0.235296 11.00000 -1.20000 AFIX 0 C23 1 0.165038 0.800162 -0.290215 11.00000 0.11639 0.08270 = 0.06408 -0.00615 0.00187 -0.00649 AFIX 43 H23 2 0.097113 0.774069 -0.324130 11.00000 -1.20000 AFIX 0 C24 1 0.351862 0.837089 -0.292681 11.00000 0.09914 0.07491 = 0.06445 0.00758 0.01574 0.01343 C25 1 0.450539 0.877620 -0.243648 11.00000 0.07098 0.09647 = 0.07164 0.01344 0.01170 0.00318 AFIX 43 H25 2 0.575572 0.903742 -0.245998 11.00000 -1.20000 AFIX 0 C26 1 0.363678 0.879688 -0.190359 11.00000 0.06776 0.07658 = 0.06658 0.00265 0.00352 -0.00173 AFIX 43 H26 2 0.431759 0.907147 -0.157005 11.00000 -1.20000 AFIX 0 N1 3 -0.025846 0.892726 0.060119 11.00000 0.06489 0.07137 = 0.05620 -0.00324 0.00179 -0.00415 N3 3 0.043694 0.870863 -0.037677 11.00000 0.07078 0.09537 = 0.05863 -0.00436 0.00893 -0.02410 N4 3 0.177022 0.874080 -0.080508 11.00000 0.06268 0.06381 = 0.06220 -0.00064 0.00640 -0.00541 O1 4 0.050000 0.948063 0.219558 11.00000 0.07176 0.07552 = 0.06273 -0.00763 -0.00455 -0.00453 CL1 5 0.462599 0.832555 -0.358839 11.00000 0.14979 0.14178 = 0.07955 0.00746 0.04331 0.02822 F1 6 -0.276138 0.510277 0.057753 11.00000 0.17584 0.09486 = 0.10498 0.01898 0.00603 -0.03077 S1 7 0.344142 0.929736 0.044101 11.00000 0.06849 0.08631 = 0.07447 -0.00310 0.00606 -0.01809 HKLF 4 REM bmk1637b in P2(1)/c REM R1 = 0.0603 for 2323 Fo > 4sig(Fo) and 0.1247 for all 4617 data REM 298 parameters refined using 0 restraints END WGHT 0.0537 0.6884 REM Highest difference peak 0.169, deepest hole -0.209, 1-sigma level 0.040 Q1 1 0.3398 0.9593 -0.0029 11.00000 0.05 0.17 Q2 1 0.5957 0.8243 -0.3358 11.00000 0.05 0.16 Q3 1 -0.4328 0.5023 0.0278 11.00000 0.05 0.15 Q4 1 -0.2156 0.8608 0.0447 11.00000 0.05 0.15 Q5 1 0.0250 0.9207 0.1359 11.00000 0.05 0.14 ; _shelx_res_checksum 43212 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy C C1 -0.0420(5) 0.9153(2) 0.16557(14) 0.0617(8) Uani d 1 C C2 -0.2264(5) 0.8840(2) 0.17209(15) 0.0666(9) Uani d 1 H H2 -0.315276 0.858931 0.141930 0.080 Uiso calc 1 C C3 -0.2636(5) 0.8956(2) 0.23330(15) 0.0659(9) Uani d 1 C C4 -0.0873(5) 0.9353(2) 0.26072(16) 0.0669(9) Uani d 1 C C5 -0.4193(6) 0.8785(3) 0.26796(18) 0.0805(11) Uani d 1 H H5 -0.538290 0.852152 0.251208 0.097 Uiso calc 1 C C6 -0.3937(7) 0.9014(3) 0.32729(19) 0.0923(12) Uani d 1 H H6 -0.497815 0.891053 0.350794 0.111 Uiso calc 1 C C7 -0.2172(8) 0.9393(3) 0.35304(18) 0.0948(13) Uani d 1 H H7 -0.204363 0.952927 0.393693 0.114 Uiso calc 1 C C8 -0.0587(7) 0.9576(3) 0.32022(18) 0.0898(12) Uani d 1 H H8 0.060249 0.983506 0.337468 0.108 Uiso calc 1 C C9 0.0725(5) 0.9187(2) 0.11473(14) 0.0591(8) Uani d 1 C C10 0.2685(5) 0.9408(2) 0.11469(16) 0.0712(10) Uani d 1 H H10 0.351786 0.959633 0.148300 0.085 Uiso calc 1 C C11 0.1001(5) 0.8959(2) 0.01989(16) 0.0637(8) Uani d 1 C C12 -0.1510(5) 0.8293(2) -0.05800(15) 0.0661(9) Uani d 1 H H12 -0.261981 0.869744 -0.052668 0.079 Uiso calc 1 C C13 -0.1304(5) 0.8178(3) -0.12471(15) 0.0810(11) Uani d 1 H H13A -0.154473 0.757287 -0.137032 0.097 Uiso calc 1 H H13B -0.224552 0.855387 -0.148931 0.097 Uiso calc 1 C C14 0.0830(5) 0.8439(2) -0.13025(15) 0.0601(8) Uani d 1 C C15 -0.1805(5) 0.7438(2) -0.02572(14) 0.0602(8) Uani d 1 C C16 -0.0221(6) 0.6941(3) 0.00002(18) 0.0819(11) Uani d 1 H H16 0.109071 0.713957 -0.001787 0.098 Uiso calc 1 C C17 -0.0516(6) 0.6161(3) 0.02832(19) 0.0900(12) Uani d 1 H H17 0.057272 0.583478 0.045913 0.108 Uiso calc 1 C C18 -0.2429(8) 0.5880(3) 0.02992(16) 0.0842(12) Uani d 1 C C19 -0.4061(6) 0.6335(3) 0.00476(17) 0.0840(12) Uani d 1 H H19 -0.536128 0.611895 0.005850 0.101 Uiso calc 1 C C20 -0.3735(5) 0.7132(3) -0.02265(15) 0.0706(10) Uani d 1 H H20 -0.483302 0.746331 -0.039096 0.085 Uiso calc 1 C C21 0.1776(5) 0.8416(2) -0.18589(14) 0.0599(8) Uani d 1 C C22 0.0785(6) 0.8020(2) -0.23703(17) 0.0777(10) Uani d 1 H H22 -0.047482 0.776451 -0.235296 0.093 Uiso calc 1 C C23 0.1650(7) 0.8002(3) -0.29021(18) 0.0883(12) Uani d 1 H H23 0.097113 0.774069 -0.324130 0.106 Uiso calc 1 C C24 0.3519(6) 0.8371(3) -0.29268(17) 0.0790(11) Uani d 1 C C25 0.4505(5) 0.8776(3) -0.24365(18) 0.0794(11) Uani d 1 H H25 0.575572 0.903742 -0.245998 0.095 Uiso calc 1 C C26 0.3637(5) 0.8797(2) -0.19036(16) 0.0706(9) Uani d 1 H H26 0.431759 0.907147 -0.157005 0.085 Uiso calc 1 N N1 -0.0258(4) 0.89273(19) 0.06012(12) 0.0645(7) Uani d 1 N N3 0.0437(4) 0.8709(2) -0.03768(13) 0.0748(8) Uani d 1 N N4 0.1770(4) 0.87408(18) -0.08051(12) 0.0629(7) Uani d 1 O O1 0.0500(3) 0.94806(16) 0.21956(10) 0.0709(6) Uani d 1 Cl Cl1 0.4626(2) 0.83256(9) -0.35884(5) 0.1214(5) Uani d 1 F F1 -0.2761(5) 0.51028(17) 0.05775(12) 0.1259(10) Uani d 1 S S1 0.34414(13) 0.92974(7) 0.04410(4) 0.0766(3) Uani d 1 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 C1 0.063(2) 0.063(2) 0.056(2) 0.0041(17) -0.0049(16) -0.0023(16) C2 0.066(2) 0.071(2) 0.060(2) 0.0049(18) -0.0033(17) -0.0044(17) C3 0.071(2) 0.062(2) 0.062(2) 0.0090(18) -0.0027(18) 0.0024(17) C4 0.075(2) 0.065(2) 0.059(2) 0.0109(18) -0.0007(18) 0.0038(17) C5 0.085(3) 0.084(3) 0.072(3) 0.000(2) 0.008(2) 0.009(2) C6 0.115(3) 0.093(3) 0.071(3) 0.009(3) 0.019(3) 0.016(2) C7 0.132(4) 0.093(3) 0.058(2) 0.006(3) 0.009(3) 0.002(2) C8 0.110(3) 0.093(3) 0.063(3) -0.003(3) -0.006(2) -0.007(2) C9 0.0597(18) 0.059(2) 0.057(2) 0.0007(16) 0.0008(16) 0.0016(16) C10 0.068(2) 0.077(2) 0.067(2) -0.0116(19) 0.0042(17) -0.0081(18) C11 0.070(2) 0.058(2) 0.063(2) -0.0065(17) 0.0039(18) 0.0037(17) C12 0.0570(18) 0.077(2) 0.063(2) -0.0064(18) 0.0009(16) -0.0006(18) C13 0.072(2) 0.109(3) 0.061(2) -0.021(2) 0.0003(18) 0.009(2) C14 0.0591(18) 0.056(2) 0.063(2) -0.0051(16) -0.0002(16) 0.0059(16) C15 0.0571(18) 0.072(2) 0.0513(19) -0.0030(18) 0.0052(15) -0.0078(16) C16 0.067(2) 0.081(3) 0.096(3) -0.007(2) 0.001(2) 0.005(2) C17 0.090(3) 0.078(3) 0.098(3) 0.000(2) -0.010(2) 0.002(2) C18 0.122(4) 0.073(3) 0.057(2) -0.016(3) 0.004(2) 0.0010(19) C19 0.082(3) 0.098(3) 0.075(3) -0.027(2) 0.023(2) -0.009(2) C20 0.061(2) 0.086(3) 0.065(2) -0.005(2) 0.0091(17) -0.0046(19) C21 0.068(2) 0.0521(19) 0.058(2) -0.0010(16) 0.0029(16) 0.0048(16) C22 0.088(3) 0.073(2) 0.071(3) -0.016(2) 0.004(2) 0.000(2) C23 0.116(3) 0.083(3) 0.064(3) -0.006(3) 0.002(2) -0.006(2) C24 0.099(3) 0.075(3) 0.064(2) 0.013(2) 0.016(2) 0.008(2) C25 0.071(2) 0.096(3) 0.072(3) 0.003(2) 0.012(2) 0.013(2) C26 0.068(2) 0.077(2) 0.067(2) -0.0017(19) 0.0035(18) 0.0026(18) N1 0.0649(16) 0.0714(19) 0.0562(17) -0.0042(14) 0.0018(14) -0.0032(14) N3 0.0708(18) 0.095(2) 0.0586(18) -0.0241(16) 0.0089(15) -0.0044(16) N4 0.0627(16) 0.0638(18) 0.0622(18) -0.0054(14) 0.0064(14) -0.0006(14) O1 0.0718(14) 0.0755(16) 0.0627(15) -0.0045(12) -0.0045(12) -0.0076(12) Cl1 0.1498(11) 0.1418(12) 0.0796(8) 0.0282(9) 0.0433(7) 0.0075(7) F1 0.176(3) 0.0949(19) 0.105(2) -0.0308(18) 0.0060(17) 0.0190(15) S1 0.0685(6) 0.0863(7) 0.0745(6) -0.0181(5) 0.0061(5) -0.0031(5) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle C2 C1 O1 110.7(3) C2 C1 C9 132.1(3) O1 C1 C9 117.1(3) C1 C2 C3 108.6(3) C1 C2 H2 125.7 C3 C2 H2 125.7 C5 C3 C4 118.5(3) C5 C3 C2 137.1(4) C4 C3 C2 104.4(3) C8 C4 O1 125.8(4) C8 C4 C3 123.6(4) O1 C4 C3 110.6(3) C6 C5 C3 118.5(4) C6 C5 H5 120.7 C3 C5 H5 120.7 C5 C6 C7 121.5(4) C5 C6 H6 119.3 C7 C6 H6 119.3 C6 C7 C8 121.9(4) C6 C7 H7 119.0 C8 C7 H7 119.0 C4 C8 C7 115.9(4) C4 C8 H8 122.0 C7 C8 H8 122.0 C10 C9 N1 115.8(3) C10 C9 C1 127.4(3) N1 C9 C1 116.8(3) C9 C10 S1 111.0(3) C9 C10 H10 124.5 S1 C10 H10 124.5 N1 C11 N3 121.2(3) N1 C11 S1 116.7(3) N3 C11 S1 122.1(3) N3 C12 C15 112.3(3) N3 C12 C13 100.4(3) C15 C12 C13 113.6(3) N3 C12 H12 110.1 C15 C12 H12 110.1 C13 C12 H12 110.1 C14 C13 C12 103.9(3) C14 C13 H13A 111.0 C12 C13 H13A 111.0 C14 C13 H13B 111.0 C12 C13 H13B 111.0 H13A C13 H13B 109.0 N4 C14 C21 122.0(3) N4 C14 C13 113.2(3) C21 C14 C13 124.7(3) C16 C15 C20 118.1(3) C16 C15 C12 122.7(3) C20 C15 C12 119.1(3) C17 C16 C15 121.9(4) C17 C16 H16 119.0 C15 C16 H16 119.0 C18 C17 C16 118.1(4) C18 C17 H17 120.9 C16 C17 H17 120.9 C17 C18 C19 122.8(4) C17 C18 F1 119.2(4) C19 C18 F1 118.0(4) C18 C19 C20 118.3(4) C18 C19 H19 120.9 C20 C19 H19 120.9 C15 C20 C19 120.7(4) C15 C20 H20 119.7 C19 C20 H20 119.7 C26 C21 C22 117.9(3) C26 C21 C14 121.9(3) C22 C21 C14 120.2(3) C23 C22 C21 120.9(3) C23 C22 H22 119.5 C21 C22 H22 119.5 C24 C23 C22 119.6(4) C24 C23 H23 120.2 C22 C23 H23 120.2 C25 C24 C23 120.7(3) C25 C24 Cl1 119.7(3) C23 C24 Cl1 119.6(3) C24 C25 C26 119.7(4) C24 C25 H25 120.1 C26 C25 H25 120.1 C21 C26 C25 121.2(3) C21 C26 H26 119.4 C25 C26 H26 119.4 C11 N1 C9 109.0(3) C11 N3 N4 121.3(3) C11 N3 C12 123.9(3) N4 N3 C12 114.4(3) C14 N4 N3 107.4(3) C4 O1 C1 105.7(3) C10 S1 C11 87.54(17) loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance C1 C2 1.341(4) C1 O1 1.388(4) C1 C9 1.442(4) C2 C3 1.433(4) C2 H2 0.9300 C3 C5 1.389(5) C3 C4 1.401(5) C4 C8 1.370(5) C4 O1 1.384(4) C5 C6 1.368(5) C5 H5 0.9300 C6 C7 1.378(6) C6 H6 0.9300 C7 C8 1.381(6) C7 H7 0.9300 C8 H8 0.9300 C9 C10 1.350(4) C9 N1 1.381(4) C10 S1 1.722(4) C10 H10 0.9300 C11 N1 1.300(4) C11 N3 1.359(4) C11 S1 1.734(3) C12 N3 1.470(4) C12 C15 1.513(5) C12 C13 1.528(5) C12 H12 0.9800 C13 C14 1.495(4) C13 H13A 0.9700 C13 H13B 0.9700 C14 N4 1.301(4) C14 C21 1.460(4) C15 C16 1.372(5) C15 C20 1.377(4) C16 C17 1.372(5) C16 H16 0.9300 C17 C18 1.349(5) C17 H17 0.9300 C18 C19 1.358(5) C18 F1 1.367(4) C19 C20 1.389(5) C19 H19 0.9300 C20 H20 0.9300 C21 C26 1.383(4) C21 C22 1.396(5) C22 C23 1.382(5) C22 H22 0.9300 C23 C24 1.373(5) C23 H23 0.9300 C24 C25 1.365(5) C24 Cl1 1.731(4) C25 C26 1.385(5) C25 H25 0.9300 C26 H26 0.9300 N3 N4 1.380(3) loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_site_symmetry_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA _geom_hbond_publ_flag C19 H19 F1 3_465 0.93 2.58 3.254(5) 130 yes _cod_database_fobs_code 1550772