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Information card for entry 7134739
Preview
| Coordinates | 7134739.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Chemical name | C1-Rh |
|---|---|
| Formula | C300 H224 Cl8 O8 P16 Rh8 |
| Calculated formula | C300 H224 Cl8 O8 P16 Rh8 |
| Title of publication | Selective Hydrosilylation of Olefins by a Two-Dimensional Rh(I) Low-Valent Metal–Organic Framework |
| Authors of publication | Mandal, Dipendu; Esposito, Madison R.; Griffin, Samuel E.; Domecus, Grant P.; Cohen, Seth M. |
| Journal of publication | Chemical Communications |
| Year of publication | 2025 |
| a | 11.6257 ± 0.0006 Å |
| b | 22.2356 ± 0.0013 Å |
| c | 46.905 ± 0.003 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 12125.1 ± 1.2 Å3 |
| Cell temperature | 100.15 K |
| Ambient diffraction temperature | 100.15 K |
| Number of distinct elements | 6 |
| Space group number | 70 |
| Hermann-Mauguin space group symbol | F d d d :2 |
| Hall space group symbol | -F 2uv 2vw |
| Residual factor for all reflections | 0.0965 |
| Residual factor for significantly intense reflections | 0.0722 |
| Weighted residual factors for significantly intense reflections | 0.1944 |
| Weighted residual factors for all reflections included in the refinement | 0.2129 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.134 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Diffraction radiation X-ray symbol | K-L~3~ |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 300133 (current) | 2025-06-20 | cif/ Adding structures of 7134739, 7134740 via cif-deposit CGI script. |
7134739.cif |
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